Publication_all of Nishi Lab

2010 - 2012


Shiomi, T.; Adachi, T.; Toribatake, K.; Zhou, L.; Nishiyama, H.
Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium-bisoxazolinylphenyl catalysts
Chem. Commun. 2009, 5987-5989 (October 28, 2009)

Mizuno, M.; Inoue, H.; Naito, T.; Zhou, L.; Nishiyama, H.
Asymmetric Regioselective Direct Aldol Coupling of Enones and Aldehydes with Chiral Rhodium(bisoxazolinylphenyl) Catalysts
Chem. Eur. J. 2009 15, 8985-8988 (Communication) (September 14, 2009)

Shiomi, T.; Adachi, T.; Ito, J.; Nishiyama, H.
Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Chiral Rh(Phebox) Catalysts
Org. Lett. 2009, 11, 1011-1014 (February 19, 2009)

Ito, J.; Ujiie, S.; Nishiyama, H.
New Bis(oxazolinyl)phenyl-Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones
Organometallics 2009, 28, 630-638 (January 26, 2009)

Inagaki, T.; Yamada, Y.; Phong, L. T.; Furuta, A.; Ito, J.; Nishiyama, H.
Catalytic Hydrosilylation of Carbonyl Compounds with Zinc(II) Acetate: Asymmetric Induction Collaborated with N
2S2 Ligands
Synlett 2009, 253-256 (January, 2009)


Hashimoto, T.; Ito, J.; Nishiyama, H.
Felkin-Anh Selectivity in Rh(bisoxazolinylphenyl) Catalyzed Reductive Aldol Coupling Reaction. Asymmetric Synthesis of Stereotriads
Tetrahedron 2008, 64, 9408-9412 (September 29, 2008)

Ito, J.; Miyakawa, T.; Nishiyama, H.
Amine-assisted C-Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Organometallics 2008, 27, 3312-3315 (June 7, 2008)

Inoue, H.; Ito, J.; Kikuchi, M.; Nishiyama, H.
Asymmetric Ligand Exchange Reaction on Biphenol Derivatives and Chiral Bis(oxazolinyl)phenyl-Rhodium Complex
Chem. Asian J. 2008, 3, 1284-1288. (May 21, 2008)

Phomkeona, K.; Takemoto, T.; Ishima, Y.; Shibatomi, K.; Iwasa, S*.; Nishiyama, H.
Chiral bis(2-oxazolinyl)xanthene (xabox)/transition-metal complexescatalyzed 1,3-dipolar cycloaddition reactions and Diels-Alder reactions
Tetrahedron 2008, 64, 1813-1822 (February 18, 2008)

Ito, J.; Ujiie, S.; Nishiyama, H.
A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones
Chem. Commun. 2008, 1923-1925. (March 12, 2008)

Inoue, H.; Kikuchi, M.; Ito, J.; Nishiyama, H.
Chiral Phebox-Rhodium Complexes as Catalysts for Asymmetric Direct Aldol Reaction
Tetrahedron 2008, 64, 493-499. (January 14, 2008)

Furuta, A.; Nishiyama, H.
Highly Efficient Catalytic System for Hydrosilylation of Ketones with Iron(II) Acetate-Thiophenecarboxylate
Tetrahedron Lett. 2008, 49, 110-113. (January 1, 2008)

[Account] Nishiyama, H.; Ito, J.; Shiomi, T.; Hashimoto, T.; Miyakawa, T.; Kitase, M.
Chiral phenyl-bis(oxazoline) as an efficient auxiliary for asymmetric catalysis
Pure Appl. Chem. 2008, 80, 743-749.


Yamamoto, Y.;* Yamashita, K.; Hotta, T.; Hashimoto, T.; Kikuchi, M.; Nishiyama, H.
Synthesis of Spirocyclic C-Arylglycosides and -Ribosides by Ruthenium-Catalyzed Cycloaddition
Chem. Asian J. 2007, 2, 1388-1399. (September 28, 2007)

Hashimoto. T; Shiomi, T.; Ito, J.; Nishiyama, H.
Asymmetric synthesis of α-chiral dihydrocinnamates by catalytic reductive aldol coupling and subsequent dehydroxylation
Tetrahedron 2007, 63, 12883-12887. (December 24, 2007)

Satake, Y.; Abe, S.; Okazaki, S.; Ban, N.; Hikage, T.; Ueno, T.; Nakajima, H.; Suzuki, A.; Yamane, T.;
Nishiyama, H.; Watanabe, Y.*
Incorporation of a Phebox Rhodium Complex into apo-Myoglobin Affords a Stable Organometallic Protein Showing Unprecedented Arrangement of the Complex in the Cavity
Organometallics 2007, 26, 4904-4908. (August 21, 2007)

Ito, J.; Kitase, M.; Nishiyama, H.
Cross-Coupling of Alkynes Catalyzed by Phebox-rhodium Acetate Complexes
Organometallics 2007, 26, 6412-6417. (Nevember 1, 2007)

Nishiyama, H.; Ishikawa, J.; Shiomi, T.
Diastereoselective reductive Mannich-type coupling of acrylates and aldimines with Rh(Phebox) catalyst
Tetrahedron Lett. 2007, 48, 7841-7844. (October 29, 2007)

Shiomi, T.; Nishiyama, H.
Intermolecular Asymmetric Reductive Aldol Reaction of Ketones as Acceptors Promoted by Chiral Rh(Phebox)Catalyst
Org. Lett. 2007, 9, 1651-1654. (March 27, 2007)

Kikuchi, M.; Inagaki, T.; Nishiyama, H.
Asymmetric Intramolecular Michael Reaction Catalyzed by Proline-Derived Small Anilides
Synlett 2007, 1075-1078. (April 2007)

Takemoto, T.; Iwasa, S.; Hamada, H.; Shibatomi, K.; Kameyama, M.; Motoyama, Y.; Nishiyama, H.
Highly efficient Suzuki-Miyaura coupling reactions catalyzed by bis(oxazolinyl)phenyl-Pd(II) complex
Tetrahedron Lett. 2007, 48, 3397-3401. (May 7, 2007)

Iizuka, Y.; Zhaoming, L.; Satoh, K.; Kamigaito, M.; Okamoto, Y.; Ito, J.; Nishiyama, H.
Chiral (-)-Diop Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions
Eur. J. Org. Chem. 2007, 782-791. (February, 2007)

[Review] Nishiyama, H.
Synthesis and use of bisoxazolinyl-phenyl pincers
Chem. Soc. Rev. 2007, 36, 1133-1141. (February 9, 2007)

[Account] Nishiyama, H.; Ito, J.
Bis(oxazolinyl)phenyl Transition Metal Complexes: Synthesis, Asymmetric Catalysis, and Coordination Chemistry
Chem. Rec. 2007, 7, 159-166.

Ito, J.; Nishiyama, H.
Carbon-Hydrogen Bond Activation of Arenes by a[Bis(oxazolinyl)phenyl]-rhodium(III) Acetate Complex
Eur. J. Inorg. Chem. 2007, 1114-1119. (March 2007)

Nishiyama, H.; Furuta, A.
An Iron-catalysed Hydrosilylation of Ketones
Chem. Commun. 2007, 760-762 (December 20, 2006)

Uchimura, H.; Ito, J.; Iwasa, S.; Nishiyama, H.
Oxidative addition reactions and stereochemistry on rhodium/4,5-bis(2-oxazolinyl)xanthene complexes
J. Organomet. Chem. 2007, 692. 481-486. (January 1, 2007)


Yamamoto, Y.; Kuwabara, S.; Hayashi, H: Nishiyama, H
onvergent Synthesis of Azabicylcoalkenones using Squaric Acid as Platform
Adv. Synth. Catal. 2006, 348, 2493-2500. (Nevember 2006)

Kanazawa, K.; Nishiyama. H.
Conjugate Reduction of
a,b-Unsaturated Aldehydes with Rhodium-(bisoxazolinylphenyl) Catalysts
Synlett 2006, 3343-3345. (December 2006)

Ito, J.; Miyakawa, T.; Nishiyama, H.
A Carbon-Carbon Bond Formation on Bis(oxazolinyl)phenyl-Rhodium Complex in Reduction and Oxidative Addition Sequence
Organometallics 2006 , 25, 5216-5218. (September 26, 2006)

Yamamoto, Y.; Hashimoto, T; Hattori, K.; Kikuchi, M.; Nishiyama, H.
Synthesis of spirocyclic C-arylribosides via cyclotrimerization
Org. Lett. 2006, 8, 3565-3568. (July 14, 2006)

Yamamoto, Y.; Hattori, K.; Nishiyama, H.
Synthesis of Bicyclic p-Diiodobenzenes via Silver-Catalyzed Csp-H Iodination and Ruthenium-Catalyzed Cycloaddition
J. Am. Chem. Soc. 2006, 128, 8336-8340. (June 8, 2006)

Yamamoto, Y.; Kinpara, K.; Ogawa, R.; Nishiyama, H.; Itoh, K.
Ruthenium-catalyzed cycloaddition of 1,6-diynes and nitriles under mild conditions: Role of the coordinating group of nitriles
Chem. Eur. J. 2006, 12, 5618-5631. (Jun 6, 2006)

Yamamoto, Y.; Suzuki, R.; Hattori, K.; Nishiyama, H.
Base- and phosphine-free palladium-catalyzed homocoupling of arylboronic acid derivatives under air
Synlett 2006, 1027-1030. (May 2006)

Shiomi, T.; Ito, J.; Yamamoto, Y.; Nishiyama, H.
4-Substituted-Phenyl(bisoxazoline)-Rhodium Complexes: Efficiency for Catalytic Asymmetric Reductive Aldol Reaction
Eur. J. Org. Chem. 2006, 5594-5600. (December 2006)

Ito, J.; Shiomi, T.; Nishiyama, H.
Efficient Preparation of New Rhodium- and Iridium-[bis(oxazolinyl)-3,5-dimethylphenyl] Complexes by C-H Bond Activation. An Application in Asymmetric Synthesis
Adv. Synth. Catal. 2006, 348, 1235-1240. (July 2006)

Motoyama Y.; Shimozono, K.; Nishiyama, H.
Novel (oxazolinyl)phenyl phosphinite pincer ligand: Development of the first non-symmetrical, PCN type chiral palladium and platinum complexes
Inorg. Chim. Acta 2006, 359, 1725-1730.

Yamamoto, Y.; Hattori, K.; Ishii, J.; Nishiyama, H.
Synthesis of arylboronates via Cp*RuCl-catalyzed cycloaddition of alkynylboronates
Tetrahedron, 2006, 62, 4294-4305.

Kanazawa, Y; Tsuchiya, Y.; Kobayashi, K.; Shiomi, T.; Itoh, J.-I.; Kikuchi, M.; Yamamoto, Y.; Nishiyama, H.
Asymmetric Conjugate Reduction of α,β-Unsaturated Ketones and Esters with Chiral Rhodium(2,6-bisoxazolinylphenyl) Catalysts
Chem. Eur. J. 2006, 12, 63-71. (September 29 2005)


Yamamoto, Y.; Kinpara, K.; Nishiyama, H.; Itoh, K
Synthesis of 2-Haloalkylpyridines via Cp*RuCl-Catalyzed Cycloaddition of 1,6-Diynes with alpha-Halonitriles. Unusual Halide Effect in Catalytic Cyclocotrimerization
Adv. Synth. Catal. 2005, 347, 1913-1916.

Yamamoto, Y.; Ishii, J.; Nishiyama, H.; Itoh, K.
One-pot sequential four-component coupling via Cp*RuCl-catalyzed cyclotrimerization and Suzuki-Miyaura coupling 
Tetrahedron 2005, 61, 11501-11510.

Yamamoto, Y.; Hayashi, H.; Saigoku, T.; Nishiyama, H.
Domino coupling relay approach to polycyclic pyrrole-2-carboxylates
J. Am. Chem. Soc. 2005, 127, 10804-10805.

Yamamoto, Y.; Ishii, J.; Nishiyama, H.; Itoh, K.
Cp*RuCl-catalyzed formal intermolecular cyclotrimerization of three unsymmetrical alkynes through a boron temporary tether: Regioselective four-component coupling synthesis of phthalides
J. Am. Chem. Soc. 2005, 127, 9625-9631.

Nishiyama, H.; Shiomi, T.; Tsuchiya, Y.; Matsuda, I.
High performance of Rh(Phebox) catalysts in asymmetric reductive aldol reaction: High anti-selectivity
J. Am. Chem. Soc. 2005, 127, 6972-6973.

Yamamoto, Y.; Hattori, K.; Ishii, J.; Nishiyama, H.; Itoh, K.
Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of alpha,omega-diynes with ethynylboronate
Chem. Commun. 2005,, 4438-4440.

Yamamoto, Y.; Saigoku, T.; Nishiyama, H.; Ohgai, T.; Itoh, K.
Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides
Org. Biomol. Chem. 2005, 3, 1768-1775.

Yamamoto, Y.; Kinpara, K.; Saigoku, F.; Takagishi, H.; Okuda, S.; Nishiyama, H.; Itoh, K.
Cp*RuCl-catalyzed [2+2+2] cycloadditions of alpha,omega-diynes with electron-deficient carbon-heteroatom multiple bonds leading to heterocycles
J. Am. Chem. Soc. 2005, 127, 605-613.

Iwasa, S.; Fakhruddin, A.; Widagdo, H. S.; Nishiyama, H.
A rapid and efficient synthesis of quinone derivatives: Ru(II)- or Ir(I)-catalyzed hydrogen peroxide oxidation of phenols and methoxyarenes
Adv. Synth. Catal. 2005, 347, 517-520.

Yamamoto, Y.; Kataoka, H.; Kinpara, K.; Nishiyama, H.; Itoh, K.
Synthesis of ferrocenylbenzenes via Cp*RuCl-catalyzed partially intramolecular cyclotrimerization of ferrocenylalkynes
Lett. Org. Chem. 2005, 2, 219-221.

Iwasa, S.; Fakhruddin, A.; Nishiyama, H.
Synthesis of acylnitroso intermediates and their synthetic applications
Mini-Reviews in Organic Chemistry 2005, 2, 157-175.


Fakhruddin, A.; Iwasa, S.; Nishiyama, H.; Tsutsumi, K.
Ene reactions of acyl nitroso intermediates with alkenes and their halocyclization
Tetrahedron Lett. 2004, 45, 9323-9326.

Yamamoto, Y.; Kuwabara, S.; Ando, Y.; Nagata, H.; Nishiyama, H.; Itoh, K.
Palladium(0)-catalyzed cyclization of electron-deficient enynes and enediynes
J. Org. Chem. 2004, 69, 6697-6705.

Yamamoto, Y.; Kuwabara, S.; Matsuo, S.; Ohno, T.; Nishiyama, H.; Itoh, K.
Synthesis and decomposition behavior of a C-2-symmetrical palladium(IV) spirocyclic complex
Organometallics 2004, 23, 3898-3906.

Yamamoto, Y.; Ishii, J. I.; Nishiyama, H.; Itoh, K.
Ru(II)-catalyzed chemo- and regioselective cyclotrimerization of three unsymmetrical alkynes through boron temporary tether. One-pot four-component coupling via cyclotrimerization/Suzuki-Miyaura coupling
J. Am. Chem. Soc. 2004, 126, 3712-3713.

Yamamoto, Y.; Saigoku, T.; Ohgai, T.; Nishiyama, H.; Itoh, K.
Synthesis of C-arylglycosides via Ru(II)-catalyzed [2+2+2] cycloaddition
Chem. Commun. 2004,, 2702-2703.

Tsuchiya, Y.; Kanazawa, Y.; Shiomi, T.; Kobayashi, K.; Nishiyama, H.
Asymmetric conjugate reduction of alpha,beta-unsaturated esters with chiral rhodium(bisoxazolinylphenyl) catalysts
Synlett 2004,, 2493-2496.

Iwasa, S.; Ishima, Y.; Widagdo, H. S.; Aoki, K.; Nishiyama, H.
Synthesis of novel chiral bis(2-oxazolinyl)xanthene (xabox) ligands and their evaluation in catalytic asymmetric 1,3-dipolar cycloaddition reactions of nitrones with 3-crotonoyl-2-oxazolidinone
Tetrahedron Lett. 2004, 45, 2121-2124.

Tsuchiya, Y.; Uchimura, H.; Kobayashi, K.; Nishiyama, H.
Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis(oxazolinyl)phenyl-rhodium complex
Synlett 2004,, 2099-2102.

Yamamoto, Y.; Kinpara, K.; Saigoku, T.; Nishiyama, H.; Itoh, K.
Synthesis of benzo-fused lactams and lactones via Ru(II)-catalyzed cycloaddition of amide- and ester-tethered alpha,omega-diynes with terminal alkynes: electronic directing effect of internal conjugated carbonyl group
Org. Biomol. Chem. 2004, 2, 1287-1294.


Motoyama, Y.; Nishiyama, H.
Bis(oxazolinyl)phenylrhodium(III) aqua complex: Efficiency in enantioselective addition of methallyltributyltin to aldehydes under aerobic conditions
Synlett 2003,, 1883-1885.

Iwasa, S.; Tsushima, S.; Nishiyama, K.; Tsuchiya, Y.; Takezawa, F.; Nishiyama, H.
Catalytic asymmetric cyclopropanation of alkenes with diazoesters in protic and biphasic media
Tetrahedron-Asymmetry 2003, 14, 855-865.

[Account] Motoyama, Y.; Nishiyama, H.
Chiral transition metal Lewis acids bearing bis(oxazolinyl)phenyl (Phebox) as a pincer ligand: Synthesis and application for the asymmetric reactions
J. Synth. Org. Chem. Jpn. 2003, 61, 343-351.