Nishiyama Paper of Nishi Lab

発表学術論文

178) Ito, J.; Ubukata, S.; Muraoka, S.; Nishiyama, H.
Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes
Chem. Eur. J. in press.

177) Naganawa, Y.; Aoyama, T.; Kato, K.; Nishiyama, H.
Cu(II)-catalyzed Enantioselective α-Hydroxylation and α-Chlorination of β-Ketoesters with N,N,O-Tridentate Chiral Phenanthroline Ligand
ChemistrySelect, 2016, 1, 1938-1942.

176) Ito, J.; Sugino, K.; Matsushima, S.; Sakaguchi, H.; Iwata, H.; Ishihara, T.; Nishiyama, H.
Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction

Organometallics 2016, 35, 1885-1894.

175) Naganawa, Y.; Abe, H.; Nishiyama, H.
Ni(II)-catalyzed Asymmetric Michael Addition of Oxindoles with Modified N,N,O-Tridentate Chiral Phenanthroline Ligands
Synlett 2016, 1973-1978.

174) Ubukata, S.; Ito, J.; Oguri, R.; Nishiyama, H.
Asymmetric Three Component Coupling Reaction of Alkyne, Enone, and Aldehyde Catalyzed by Chiral Phebox Ruthenium Catalysts
J. Org. Chem. 2016, 81, 3347-3355.

173) Naganawa, Y.; Kawagishi, M.; Ito, J.; Nishiyama, H.
Asymmetric Induction at Remote All-carbon Quaternary Centers of Cyclohexadienones by Rh-catalyzed Conjugate Hydrosilylation
Angew. Chem. Int. Ed. 2016, 55, 6873-6876.

172) Naganawa, Y.; Aoyama, T.; Nishiyama, H.
Cu(II)-catalyzed enantioselective oxygen atom transfer from oxaziridine to oxindole derivatives with chiral phenanthroline
Org. Biomol. Chem.2015, 13, 11499-11506.

171) Naganawa, Y.; Komatsu, H.; Nishiyama, H.
Zinc-catalyzed Enantioselective Electrophilic Amination of β-Ketocarbonyl Compounds with Axially Chiral Phenanthroline Ligands
Chem. Lett.
2015, 44, 1652-1654.

170) Ito, J.; Miyakawa, T.; Nishiyama, H.
Asymmetric β-Functionalization of Secondary Amine with CH2Cl2 on a Chiral NCN Pincer Rh Complex
J. Organomet. Chem. 2015, 794, 318-322.

169) Naganawa, Y.; Namba, T.; Kawagishi, M.; Nishiyama, H.
Construction of Chiral Silicon Center via Rh-Catalyzed Enantioselective Intramolecular Hydrosilylation
Chem. Eur. J. 2015,21, 9319-9322

168) Toribatake, K.; Miyata, S.; Naganawa, Y.; Nishiyama H.
Asymmetric synthesis of optically active 3-amino-1,2-diols from N-acyl-protected allylamines via catalytic diboration with Rh[bis(oxazolinyl)phenyl] catalysts
Tetrahedron. 2015, 71, 3203-3208.

167) Ito, J.; Hosokawa, S.; Hairuzana B. K.; Nishiyama, H.
Preparation, Characterization, and Catalytic Reactions of NCN Pincer Iron Complexes Containing Stannyl, Silyl, Methyl, and Phenyl Ligands
Organometallics 2015, 34, 1377-1383

166) Naganawa, Y.; Namba, T.; Aoyama, T.; Shoji, K.; Nishiyamam H.
Design of novel chiral N,N,O-tridentate phenanthroline ligands and its application to enantioselective addition of organozinc reagents to aldehydes
Chem. Commun., 2014, 50, 13224-13227

165) Toribatake, K.; Nishiyama, H.
Asymmetric diboration of terminal alkenes with rhodium catalyst and subsequent oxidation: Enantioselective synthesis of optically active 1,2-diols
Angew. Chem. Int. Ed. 2013, 52, 11011-11015.

164) Hosokawa, S.; Ito, J.; Nishiyama
NCN-Pincer Cobalt Complexes Containing Bis(oxazolinyl)phenyl Ligands
Organometallics 2013, 32, 3980-3985.

163) Toribatake, K.; Zhou, L.; Tsuruta, A.; Nishiyama, H.
Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalyst
Tetrahedron, 2013, 69, 3551-3560.

162) Ito, J.; Fujii, K.; Nishiyama, H.
Direct Conjugate Addition of Alkynes with a,b-Unsaturated Carbonyl Compounds Catalyzed by NCN Pincer Ru Complexes
Chem. Eur. J, .2013, 19, 601-605.

161) Itoh, K.; Tsuruta, A.; Ito, J.; Yamamoto, Y.; Nishiyama, H.
Enantioselective Synthesis of Optically Active 3,3-Diarylpropanoates by Conjugate Hydrosilylation with Chiral Rh-bis(oxazolinyl)phenyl Catalysts
J. Org. Chem. 2012, 77, 10914-10919.

160) Hosokawa, S.; Ito, J.; Nishiyama, H.
Change in Coordination of NCN Pincer Iron Complexes Containing Bis(oxazolinyl)phenyl Ligands
Organometallics, 2012, 31, 8283-8290

159) Naito, T.; Yoneda, T.; Ito, J.; Nishiyama, H.
Enantioselective Hydrosilylation of Aromatic Alkenes Catalyzed by Chiral Bis(oxazolinyl)phenyl Rhodium Acetate Complexes
Synlett, 2012, 23, 2957-2960.

158) Yamamoto, Y.; Fukatsu, K.; Nishiyama, H.
Ruthenium-catalyzed hydrophosphinylative cyclization of 1,6-diynes. Stereoselective synthesis of exocyclic 1,3-dienylphosphine oxides
Chem. Commun., 2012, 48, 7985-7987

157) Yamashita, K.; Yamamoto, Y.; Nishiyama, H.
Ruthenium-Catalyzed Transfer Oxygenative Cyclization of α,ω-Diynes: Unprecedented [2 + 2 + 1] Route to Bicyclic Furans via Ruthenacyclopentatriene
J. Am. Chem. Soc.2012, 134, 7660-7663.

156) Ito, J.; Kaneda, T.; Nishiyama, H.
Intermolecular C?H Bond Activation of Alkanes and Arenes by NCN Pincer Iridium(III) Acetate Complexes Containing Bis(oxazolinyl)phenyl Ligands
Organometallics 2012, 31, 4442-4449.

155) Yamamoto, Y.; Yamada, S.; Nishiyama, H.
Copper-Catalyzed Regio- and Stereoselective Conjugate Allylation of Electron-Deficient Alkynes with Allylboronates under Mild Conditions
Chem. Eur. J. 2012, 18, 3153-3156.

154) Ito, J.; Teshima, T.; Nishiyama, H.
Enhancement of Enantioselectivity by Alcohol Additives in Asymmetric Hydrogenation with Bis(oxazolinyl)phenyl Ruthenium Catalysts
Chem. Commun. 2012, 48, 1105-1107.

153) Yamashita, K.; Nagashima, Y.; Yamamoto, Y.; Nishiyama, H.
Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activation via metallacyclopentatriene
Chem. Commun. 2011, 47, 11552-11554.

152) Motoyama, Y.; Sakakura, T.; Takemoto, T.; Shimozono, K.; Aoki, K.; Nishiyama, H.
Enantioselective Addition of Allyltin Reagents to Amino Aldehydes Catalyzed with Bis(oxazolinyl)phenylrhodium(III) Aqua Complexes
Molecules 2011, 16, 5387-5401.

151) Ohshima,T.*; Kawabata, T.; Takeuchi, Y,; Kakinuma, T.; Iwasaki, T.; Yonezawa, T.; Murakami, H.; Nishiyama, H.; Mashima, K.*,
C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of α-Ketoesters
Angew. Chem. Int. Ed., 2011, 50, 6296-6300.

150) Yamamoto, Y.; Yamada, S.; Nishiyama, H.
Synthesis of 3-Arylindole-2-carboxylates via Copper-Catalyzed Hydroarylation of o-Nitrophenyl-Substituted Alkynoates and Subsequent Cadogan Cyclization
Adv. Synth. Catal. 2011, 353, 701-706.

149) Klare, H. F. T.; Oestreich, M.; Ito, J.; Nishiyama, H.; Ohki, Y.; Tatsumi, K.
Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
J. Am. Chem. Soc. 2011, 133, 3312-33115.

148) Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynes
Yamamoto, Y.; Yamashita, K.; Nishiyama, H.
Chem. Commun., 2011, 47, 1556-1558.

147) Hosokawa, S.; Ito, J.; Nishiyama, H.
A Chiral Iron Complex Containing a Bis(oxazolinyl)phenyl Ligand: Preparation and Asymmetric Hydrosilylation of Ketones
Organometallics 2010, 29, 5773-5775.

146) Inagaki, T.; Ito, A.; Ito, J.; Nishiyama, H.
Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration
Angew. Chem. Int. Ed. 2010, 49, 9384-9387.

145) Ito, J.; Asai, R.; Nishiyama, H.
Asymmetric Direct Alkynylation Catalyzed by Chiral Ru-Bis(oxazolinyl)phenyl Complexes
Org. Lett. 2010, 12, 3860-3862.

144) Ito, J.; Ujiie, S.; Nishiyama, H.
Chiral Bis(oxazolinyl)phenyl Ru(II) Catalysts for Highly Enantioselective Cyclopropanation
Chem. Eur. J. 2010, 16, 4986-4990 (Communication).

143) Inagaki, T.; Le, T. P.; Furuta, A.; Ito, J.; Nishiyama, H.
Iron- and Cobalt Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
Chem. Eur. J. 2010, 16, 3090-3096 (Full Paper).

142) Shiomi, T.; Adachi, T.; Toribatake, K.; Zhou, L.; Nishiyama, H.
Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium-bisoxazolinylphenyl catalysts
Chem. Commun. 2009, 5987-5989.

141) Mizuno, M.; Inoue, H.; Naito, T.; Zhou, L.; Nishiyama, H.
Asymmetric Regioselective Direct Aldol Coupling of Enones and Aldehydes with Chiral Rhodium(bis-oxazolinylphenyl) Catalysts
Chem. Eur. J. 2009, 15, 8985-8988 (Communication)

140) Shiomi, T.; Adachi, T.; Ito, J.; Nishiyama, H.
Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Chiral Rh(Phebox) Catalysts
Org. Lett. 2009, 11, 1011-1014.

139) Ito, J.; Ujiie, S.; Nishiyama, H.
New Bis(oxazolinyl)phenyl-Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones
Organometallics 2009, 28, 630-638.

138) Inagaki, T.; Yamada, Y.; Phong, L. T.; Furuta, A.; Ito, J.; Nishiyama, H.
Catalytic Hydrosilylation of Carbonyl Compounds with Zinc(II) Acetate: Asymmetric Induction Collaborated with N2S2 Ligands
Synlett 2009, 253-256.

137) Hashimoto, T.; Ito, J.; Nishiyama, H.
Felkin-Anh Selectivity in Rh(bisoxazolinylphenyl) Catalyzed Reductive Aldol Coupling Reaction. Asymmetric Synthesis of Stereotriads
Tetrahedron 2008, 64, 9408-9412

136) Ito, J.; Miyakawa, T.; Nishiyama, H.
Amine-assisted C-Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Organometallics 2008, 27, 3312-3315.

135) Inoue, H.; Ito, J.; Kikuchi, M.; Nishiyama, H.
Asymmetric Ligand Exchange Reaction on Biphenol Derivatives and Chiral Bis(oxazolinyl)phenyl-Rhodium Complex
Chem. Asian J. 2008, 3, 1284-1288.

134) Phomkeona, K.; Takemoto, T.; Ishima, Y.; Shibatomi, K.; Iwasa, S*.; Nishiyama, H.
Chiral bis(2-oxazolinyl)xanthene (xabox)/transition-metal complexescatalyzed 1,3-dipolar cycloaddition reactions and Diels-Alder reactions
Tetrahedron 2008, 64, 1813-1822.

133) Ito, J.; Ujiie, S.; Nishiyama, H.
A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones
Chem. Commun. 2008, 1923-1925.

132) Inoue, H.; Kikuchi, M.; Ito, J.; Nishiyama, H.
Chiral Phebox-Rhodium Complexes as Catalysts for Asymmetric Direct Aldol Reaction
Tetrahedron 2008, 64, 493-499.

131) Furuta, A.; Nishiyama, H.
Highly Efficient Catalytic System for Hydrosilylation of Ketones with Iron(II) Acetate-Thiophenecarboxylate
Tetrahedron Lett. 2008, 49, 110-113.

130) Yamamoto, Y.;* Yamashita, K.; Hotta, T.; Hashimoto, T.; Kikuchi, M.; Nishiyama, H.
Synthesis of Spirocyclic C-Arylglycosides and -Ribosides by Ruthenium-Catalyzed Cycloaddition
Chem. Asian J. 2007, 2, 1388-1399.

129) Hashimoto. T; Shiomi, T.; Ito, J.; Nishiyama, H.
Asymmetric synthesis of a-chiral dihydrocinnamates by catalytic reductive aldol coupling and subsequent dehydroxylation
Tetrahedron 2007, 63, 12883-12887.

128) Satake, Y.; Abe, S.; Okazaki, S.; Ban, N.; Hikage, T.; Ueno, T.; Nakajima, H.; Suzuki, A.; Yamane, T.; Nishiyama, H.; Watanabe, Y.*
Incorporation of a Phebox Rhodium Complex into apo-Myoglobin Affords a Stable Organometallic Protein Showing Unprecedented Arrangement of the Complex in the Cavity
Organometallics 2007, 26, 4904-4908.

127) Ito, J.; Kitase, M.; Nishiyama, H.
Cross-Coupling of Alkynes Catalyzed by Phebox-rhodium Acetate Complexes
Organometallics 2007, 26, 6412-6417.

126) Nishiyama,H.; Ishikawa, J.; Shiomi, T.
Diastereoselective reductive Mannich-type coupling of acrylates and aldimines with
Rh(Phebox) catalyst
Tetrahedron Lett. 2007, 48, 7841-7844.

125) Shiomi, T.; Nishiyama, H.
Intermolecular Asymmetric Reductive Aldol Reaction of Ketones as Acceptors Promoted by Chiral Rh(Phebox)Catalyst
Org. Lett. 2007, 9, 1651-1654.

124) Kikuchi, M.; Inagaki, T.; Nishiyama, H.
Asymmetric Intramolecular Michael Reaction Catalyzed by Proline-Derived Small Anilides
Synlett 2007, 1075-1078.

123) Takemoto, T.; Iwasa, S.; Hamada, H.; Shibatomi, K.; Kameyama, M.; Motoyama, Y.; Nishiyama, H.
Highly efficient Suzuki-Miyaura coupling reactions catalyzed by bis(oxazolinyl)phenyl-Pd(II) complex
Tetrahedron Lett. 2007, 48, 3397-3401.

122) Iizuka, Y.; Zhaoming, L.; Satoh, K.; Kamigaito, M.; Okamoto, Y.; Ito, J.; Nishiyama, H.
Chiral (-)-Diop Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions
Eur. J. Org. Chem. 2007, 782-791.

121) Ito, J.; Nishiyama, H.
Carbon-Hydrogen Bond Activation of Arenes by a [Bis(oxazolinyl)phenyl]-rhodium(III) Acetate Complex
Eur. J. Inorg. Chem. 2007, 1114-1119.

120) Nishiyama, H.; Furuta, A.
An Iron-catalysed Hydrosilylation of Ketones
Chem. Commun. 2007, 760-762.

119) Uchimura, H.; Ito, J.; Iwasa, S.; Nishiyama, H.
Oxidative addition reactions and stereochemistry on rhodium/4,5-bis(2-oxazolinyl)xanthene complexes
J. Organomet. Chem. 2007, 692, 481-486.

118) Yamamoto, Y.; Kuwabara, S.; Hayashi, H: Nishiyama, H
Convergent Synthesis of Azabicylcoalkenones using Squaric Acid as Platform
Adv. Synth. Catal. 2006, 348, 2493-2500.

117) Kanazawa, Y.; Nishiyama. H.
Conjugate Reduction of a,b-Unsaturated Aldehydes with Rhodium-(bisoxazolinylphenyl) Catalysts
Synlett 2006, 3343-3345.

116) Yamamoto, Y.; Hashimoto, T; Hattori, K.; Kikuchi, M.; Nishiyama, H.
Synthesis of spirocyclic C-arylribosides via cyclotrimerization
Org. Lett. 2006, 8, 3565-3568.

115) Yamamoto, Y.; Hattori, K.; Nishiyama, H.
Synthesis of Bicyclic p-Diiodobenzenes via Silver-Catalyzed Csp-H Iodination and Ruthenium-Catalyzed Cycloaddition
J. Am. Chem. Soc. 2006, 128, 8336-8340.

114) Yamamoto, Y.; Kinpara, K.; Ogawa, R.; Nishiyama, H.; Itoh, K.
Ruthenium-catalyzed cycloaddition of 1,6-diynes and nitriles under mild conditions: Role of the coordinating group of nitriles
Chem. Eur. J. 2006, 12, 5618-5631.

113) Yamamoto, Y.; Suzuki, R.; Hattori, K.; Nishiyama, H.
Base- and phosphine-free palladium-catalyzed homocoupling of arylboronic acid derivatives under air
Synlett 2006, 1027-1030.

112) Ito, J.; Miyakawa, T.; Nishiyama, H.
A Carbon-Carbon Bond Formation on a Bis(oxazolinyl)phenyl-Rhodium Complex in a Reduction and Oxidative Addition Sequence
Organometallics 2006, 25, 5216-5218

111) Shiomi, T.; Ito, J.; Yamamoto, Y.; Nishiyama, H.
4-Substituted-Phenyl(bisoxazoline)-Rhodium Complexes: Efficiency for Catalytic Asymmetric Reductive Aldol Reaction
Eur. J. Org. Chem. 2006, 5594-5600.

110) Ito, J.; Shiomi, T.; Nishiyama, H.
Efficient Preparation of New Rhodium- and Iridium-[bis(oxazolinyl)-3,5-dimethylphenyl] Complexes by C-H Bond Activation. An Application in Asymmetric Synthesis
Adv. Synth. Catal. 2006, 348, 1235-1240.

109) Motoyama Y.; Shimozono, K.; Nishiyama, H.
Novel (oxazolinyl)phenyl phosphinite pincer ligand: Development of the first non-symmetrical, PCN type chiral palladium and platinum complexes
Inorg. Chim. Acta 2006, 359, 1725-1730.

108) Yamamoto, Y.; Hattori, K.; Ishii, J.; Nishiyama, H.
Synthesis of arylboronates via Cp*RuCl-catalyzed cycloaddition of alkynylboronates
Tetrahedron 2006, 62, 4294-4305.

107) Kanazawa, Y; Tsuchiya, Y.; Kobayashi, K.; Shiomi, T.; Itoh, J.-I.; Kikuchi, M.; Yamamoto, Y.; Nishiyama, H.
Asymmetric Conjugate Reduction of α,β-Unsaturated Ketones and Esters with Chiral Rhodium(2,6-bisoxazolinylphenyl) Catalysts
Chem. Eur. J. 2006, 12, 63-71.

106) Yamamoto, Y.; Kinpara, K.; Nishiyama, H.; Itoh, K
Synthesis of 2-Haloalkylpyridines via Cp*RuCl-Catalyzed Cycloaddition of 1,6-Diynes with alpha-Halonitriles. Unusual Halide Effect in Catalytic Cyclocotrimerization
Adv. Synth. Catal. 2005, 347, 1913-1916.

105) Yamamoto, Y.; Ishii, J.; Nishiyama, H.; Itoh, K.
One-pot sequential four-component coupling via Cp*RuCl-catalyzed cyclotrimerization and Suzuki-Miyaura coupling
Tetrahedron 2005, 61, 11501-11510.

104) Yamamoto, Y.; Hayashi, H.; Saigoku, T.; Nishiyama, H.
Domino coupling relay approach to polycyclic pyrrole-2-carboxylates
J. Am. Chem. Soc. 2005, 127, 10804-10805.

103) Yamamoto, Y.; Ishii, J.; Nishiyama, H.; Itoh, K.
Cp*RuCl-catalyzed formal intermolecular cyclotrimerization of three unsymmetrical alkynes through a boron temporary tether: Regioselective four-component coupling synthesis of phthalides
J. Am. Chem. Soc. 2005, 127, 9625-9631.

102) Nishiyama, H.; Shiomi, T.; Tsuchiya, Y.; Matsuda, I.
High performance of Rh(Phebox) catalysts in asymmetric reductive aldol reaction: High anti-selectivity
J. Am. Chem. Soc. 2005, 127, 6972-6973.

101) Yamamoto, Y.; Hattori, K.; Ishii, J.; Nishiyama, H.; Itoh, K.
Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of alpha,omega-diynes with ethynylboronate
Chem. Commun. 2005, 4438-4440.

100) Yamamoto, Y.; Saigoku, T.; Nishiyama, H.; Ohgai, T.; Itoh, K.
Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides
Org. Biomol. Chem. 2005, 3, 1768-1775.

99) Yamamoto, Y.; Kinpara, K.; Saigoku, F.; Takagishi, H.; Okuda, S.; Nishiyama, H.; Itoh, K.
Cp*RuCl-catalyzed [2+2+2] cycloadditions of alpha,omega-diynes with electron-deficient carbon-heteroatom multiple bonds leading to heterocycles
J. Am. Chem. Soc. 2005, 127, 605-613.

98) Iwasa, S.; Fakhruddin, A.; Widagdo, H. S.; Nishiyama, H.
A rapid and efficient synthesis of quinone derivatives: Ru(II)- or Ir(I)-catalyzed hydrogen peroxide oxidation of phenols and methoxyarenes
Adv. Synth. Catal. 2005, 347, 517-520.

97) Yamamoto, Y.; Kataoka, H.; Kinpara, K.; Nishiyama, H.; Itoh, K.
Synthesis of ferrocenylbenzenes via Cp*RuCl-catalyzed partially intramolecular cyclotrimerization of ferrocenylalkynes
Lett. Org. Chem. 2005, 2, 219-221.

96) Fakhruddin, A.; Iwasa, S.; Nishiyama, H.; Tsutsumi, K.
Ene reactions of acyl nitroso intermediates with alkenes and their halocyclization
Tetrahedron Lett. 2004, 45, 9323-9326.

95) Yamamoto, Y.; Kuwabara, S.; Ando, Y.; Nagata, H.; Nishiyama, H.; Itoh, K.
Palladium(0)-catalyzed cyclization of electron-deficient enynes and enediynes
J. Org. Chem. 2004, 69, 6697-6705.

94) Yamamoto, Y.; Kuwabara, S.; Matsuo, S.; Ohno, T.; Nishiyama, H.; Itoh, K.
Synthesis and decomposition behavior of a C-2-symmetrical palladium(IV) spirocyclic complex
Organometallics 2004, 23, 3898-3906.

93) Yamamoto, Y.; Ishii, J. I.; Nishiyama, H.; Itoh, K.
Ru(II)-catalyzed chemo- and regioselective cyclotrimerization of three unsymmetrical alkynes through boron temporary tether. One-pot four-component coupling via cyclotrimerization/Suzuki-Miyaura coupling
J. Am. Chem. Soc. 2004, 126, 3712-3713.

92) Yamamoto, Y.; Saigoku, T.; Ohgai, T.; Nishiyama, H.; Itoh, K.
Synthesis of C-arylglycosides via Ru(II)-catalyzed [2+2+2] cycloaddition
Chem. Commun. 2004, 2702-2703.

91) Tsuchiya, Y.; Kanazawa, Y.; Shiomi, T.; Kobayashi, K.; Nishiyama, H.
Asymmetric conjugate reduction of alpha,beta-unsaturated esters with chiral rhodium(bisoxazolinylphenyl) catalysts
Synlett 2004, 2493-2496.

90) Iwasa, S.; Ishima, Y.; Widagdo, H. S.; Aoki, K.; Nishiyama, H.
Synthesis of novel chiral bis(2-oxazolinyl)xanthene (xabox) ligands and their evaluation in catalytic asymmetric 1,3-dipolar cycloaddition reactions of nitrones with 3-crotonoyl-2-oxazolidinone
Tetrahedron Lett. 2004, 45, 2121-2124.

89) Tsuchiya, Y.; Uchimura, H.; Kobayashi, K.; Nishiyama, H.
Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis(oxazolinyl)phenyl-rhodium complex
Synlett 2004, 2099-2102.

88) Yamamoto, Y.; Kinpara, K.; Saigoku, T.; Nishiyama, H.; Itoh, K.
Synthesis of benzo-fused lactams and lactones via Ru(II)-catalyzed cycloaddition of amide- and ester-tethered alpha,omega-diynes with terminal alkynes: electronic directing effect of internal conjugated carbonyl group
Org. Biomol. Chem. 2004, 2, 1287-1294.

87) Motoyama, Y.; Nishiyama, H.
Bis(oxazolinyl)phenylrhodium(III) aqua complex: Efficiency in enantioselective addition of methallyltributyltin to aldehydes under aerobic conditions
Synlett 2003, 1883-1885.

86) Iwasa, S.; Tsushima, S.; Nishiyama, K.; Tsuchiya, Y.; Takezawa, F.; Nishiyama, H.
Catalytic asymmetric cyclopropanation of alkenes with diazoesters in protic and biphasic media
Tetrahedron-Asymmetry 2003, 14, 855-865.

<1980-2002>

85) Iwasa, S.; Maeda, H.; Nishiyama, K.; Tsushima, S.; Tsukamoto, Y.; Nishiyama, H.
A highly enantioselective 1,3-dipolar cycloaddition reaction in alcoholic media: Ni(II)-pybox-tipsom catalyst
Tetrahedron 2002, 58, 8281-8287.

84) Iwasa, S.; Fakhruddin, A.; Tsukamoto, Y.; Kameyama, M.; Nishiyama, H.
Iridium(I)-catalyzed hydrogen peroxide oxidation of hydroxamic acids and hetero Diels-Alder reaction of the acyl nitroso intermediates with cyclopentadiene
Tetrahedron Lett. 2002, 43, 6159-6161.

83) Motoyama, Y.; Kawakami, H.; Shimozono, K.; Aoki, K.; Nishiyama, H.
Synthesis and X-ray crystal structures of bis(oxazolinyl)phenyl-derived chiral palladium(II) and platinum(II) and -(IV) complexes and their use in the catalytic asymmetric aldol-type condensation of isocyanides and aldehydes
Organometallics 2002, 21, 3408-3416.

82) Motoyama, Y.; Koga, Y.; Kobayashi, K.; Aoki, K.; Nishiyama, H.
Novel asymmetric Michael addition of alpha-cyanopropionates to acrolein by the use of a bis(oxazolinyl)phenylstannane-derived rhodium(III) complex as a chiral Lewis acid catalyst
Chem. Eur. J. 2002, 8, 2968-2975.

81) Nishiyama, H.; Niwa, E.; Inoue, T.; Ishima, Y.; Aoki, K.
Novel metallacycle complexes from bis(oxazolinyl)pyridine-rhodium(I) species and diynes
Organometallics 2002, 21, 2572-2574.

80) Nishiyama, H.; Konno, M.; Aoki, K.
Facile formation of chloro - eta(3)-allyl complexes by reaction of vinyldiazoacetates and ruthenium(II) arene complexes
Organometallics 2002, 21, 2536-2539.

79) Motoyama, Y.; Shimozono, K.; Aoki, K.; Nishiyama, H.
Formation of Fischer carbene complexes in asymmetric aldol-type condensation of an isocyanide component on bis(oxazolinyl)phenylrhodium(III) complexes with aldehydes: Stereochemistry, structural characterization, and mechanistic studies
Organometallics 2002, 21, 1684-1696.

78) Iwasa, S.; Morita, K.; Tajima, K.; Fakhruddin, A.; Nishiyama, H.
Catalytic oxidation of alcohols with Ru(Pybox)(Pydic) complex
Chem. Lett. 2002, 284-285.

77) Iwasa, S.; Tsushima, S.; Shimada, T.; Nishiyama, H.
Chiral bis(trialkylsiloxymethyloxazolinyl)pyridine ligands. Highly enantioselective 1,3-dipolar cycloaddition reactions
Tetrahedron 2002, 58, 227-232.

76) Singh, U. P.; Babbar, P.; Hassler, B.; Nishiyama, H.; Brunner, H.
Optically active pyrazolylborate: synthesis, characterization and uses in enantioselective cyclopropanation reaction
J. Mol. Cat., Chem. 2002, 185, 33-39.

75) Iwasa, S.; Tsushima, S.; Shimada, T.; Nishiyama, H.
Synthesis of 2,6-bis(4R-trialkylsiloxymethyloxazolinyl)pyridines and their use in catalytic asymmetric 1,3-dipolar cycloaddition reactions of nitrones and activated alkenes
Tetrahedron Lett. 2001, 42, 6715-6717.

74) Iwasa, S.; Tajima, K.; Tsushima, S.; Nishiyama, H.
A mild oxidation method of hydroxamic acids: efficient trapping of acyl nitroso intermediates
Tetrahedron Lett. 2001, 42, 5897-5899.

73) Sekar, G.; Nishiyama, H.
Nonenzymatic kinetic resolution of secondary alcohols: Enantioselective S(N)2 displacement of hydroxy groups by halogens in the presence of chiral BINAP
J. Am. Chem. Soc. 2001, 123, 3603-3604.

72) Motoyama, Y.; Okano, M.; Narusawa, H.; Makihara, N.; Aoki, K.; Nishiyama, H.
Bis(oxazolinyl)phenylrhodium(III) aqua complexes: Synthesis, structure, enantioselective allylation of aldehydes, and mechanistic studies
Organometallics 2001, 20, 1580-1591.

71) Sekar, G.; Nishiyama, H.
Nonenzymatic kinetic resolution of beta-amino alcohols: chiral BINAP mediated S(N)2 displacement of hydroxy groups by halogens through formation of an aziridinium ion intermediate
Chem. Commun. 2001, 1314-1315.

70) Motoyama, Y.; Koga, Y.; Nishiyama, H.
Asymmetric hetero Diels-Alder reaction of Danishefsky's dienes and glyoxylates with chiral bis(oxazolinyl)phenylrhodium(III) aqua complexes, and its mechanistic studies
Tetrahedron 2001, 57, 853-860.

69) Iwasa, S.; Takezawa, F.; Tuchiya, Y.; Nishiyama, H.
Asymmetric cyclopropanation in protic media conducted by chiral bis(hydroxymethyl-dihydrooxazolyl)pyridine-ruthenium catalysts
Chem. Commun. 2001, 59-60.

68) Wakita, H.; Yoshiwara, H.; Kitano, Y.; Nishiyama, H.; Nagase, H.
Preparative resolution of 2-methyl-4-hexynic acid for the synthesis of optically active m-phenylene PGI(2) derivatives and determination of their absolute configuration
Tetrahedron-Asymmetry 2000, 11, 2981-2989.

67) Wakita, H.; Yoshiwara, H.; Nishiyama, H.; Nagase, H.
Total synthesis of optically active m-phenylene PGI(2) derivative: Beraprost
Heterocycles 2000, 53, 1085.

66) Motoyama, Y.; Kurihara, O.; Murata, K.; Aoki, K.; Nishiyama, H.
Chiral ruthenium-bis(oxazolinyl)]pyridine complexes of alpha,beta-unsaturated carbonyl compounds: Enantioface-selective coordination of olefins
Organometallics 2000, 19, 1025-1034.

65) Iwasa, S.; Nakamura, H.; Nishiyama, H.
A synthesis of 2,6-bis(4R-hydroxymethyloxazolyl)pyridine as a water soluble ligand
Heterocycles 2000, 52, 939-944.

64) Motoyama, Y.; Mikami, Y.; Kawakami, H.; Aoki, K.; Nishiyama, H.
Stereochemistry in asymmetric alkylation of aldimine via chiral bis(oxazolyl)phenylplatinum complexes
Organometallics 1999, 18, 3584-3588.

63) Nishiyama, H.; Naitoh, T.; Motoyama, Y.; Aoki, K.
Chiral bis(dihydrooxazolyl)pyridineruthenium complexes of trans-cycloodene and trans-cycloheptene
Chem. Eur. J. 1999, 5, 3509-3513.

62) Nishiyama, H.
Chiral bis(oxazolyl)pyridine (Pybox): Its chemistry of ruthenium complexes and asymmetric catalysis
Enantiomer 1999, 4, 569-574.

61) Motoyama, Y.; Narusawa, H.; Nishiyama, H.
Chiral Bis(oxazolinyl)phenylrhodium(III) Complexes as Lewis Acid Catalysts for Enantioselective Allylation of Aldehydes
Chem. Commun. 1999, 131-132.

60) Nishiyama, H.; Soeda, N.; Naito, T.; Motoyama, Y.
Single-chiral Bis(oxazolinyl)pyridine (pybox). Efficiency in Asymmetric Catalytic Cyclopropanation
Tetrahedron-Asymmetry 1998, 9, 2865-2869.

59) Motoyama, Y.; Murata, K.; Kurihara, O.; Naitoh, T.; Aoki, K.; Nishiyama, H.
Enantiofacially Selective Olefin Coordination of α,β-Unsaturated Carbonyl Compounds to Chiral Bis(oxazolinyl)pyridineruthenium Fragments
Organometallics 1998, 17, 1251-1253.

58) Nishiyama, H.; Sakata, N.; Sugimoto, H.; Motoyama, Y.; Wakita, H.; Nagase, H.
Synthesis of Optically Active Cyclopenta[b]benzofuran as a Precursor of m-Phenyleneprostacyclin
Synlett 1998, 930.

57) Nishiyama, H.; Shimada, T.; Itoh, H.; Sugiyama, H.; Motoyama, Y.
Novel Ruthenium-Pyridinedicarboxylate Complexes of Terpyridine and Chiral Bis(oxazolinyl)pyridine: a New Catalytic System for Alkene Epoxidation with [Bis(acetoxy)iodo]benzene as an Oxygen Donor
Chem. Commun. 1997, 1863-1864.

56) Nishiyama, H.; Sakata, N.; Motoyama, Y.; Wakita, H.; Nagase, H.
Asymmetric Induction in Intramolecular SN2' Reaction. Enantioselective Synthesis of Cyclopenta[b]benzofuran with Chiral Lithium
Synlett 1997, 1147.

55) Motoyama, Y.; Makihara, N.; Mikami, Y.; Aoki, K.; Nishiyama, H.
Chiral Bis(oxazolinyl)phenyl Rhodium and Palladium Complexes
Chem. Lett. 1997, 951-952.

54) Doyle, M. P.; Peterson, C. S.; Zhou, Q. L.; Nishiyama, H.
Comparative Evaluation of Enantiocontrol for Intramolecular Cyclopropanation of Diazoacetates with Chiral CuI, RhII and RuII Catalysts
Chem. Commun. 1997, 211-212.

53) Nishiyama, H.; Aoki, K.; Itoh, H.; Iwamura, T.; Sakata, N.; Kurihara, O.; Motoyama, Y.
Stable Decarbonylcarbene Complexes of Bis(oxazolinyl)pyridine Ruthenium and Osmium
Chem. Lett. 1996, 1071-1072.

52) Park, S. B.; Sakata, N.; Nishiyama, H.
Aryloxycarbonylcarbene Complexes of Bis(oxazolinyl)pyridineruthenium as Active Intermediates in Asymmetric Catalytic Cyclopropanations
Chem. Eur. J. 1996, 2, 303-306.

51) Nishiyama, H.
51. Catalytic Asymmetric Synthesis of Cyclopropane Derivatives on Chiral Rhodium Complexes - Isolation of Carbene Complex as Intermediate
Zhurnal Organicheskoi Khimii 1996, 32, 180-186.

50) Park, S. B.; Murata, K.; Matsumoto, H.; Nishiyama, H.
Remote Electronic Control in Asymmetric Cyclopropanation with Chiral Ru-Pybox Catalysts
Tetrahedron-Asymmetry 1995, 6, 2487-2494.

49) Aoki, K.; Murayama, K.; Nishiyama, H.
Cation-Pi Interaction between the Trimethylammonium Moiety and the Aromatic Ring with Indole-3-Acetic-Acid Choline Ester, a Model-Compound for Molecular Recognition between Acetylcholine and Its Esterase - an X-Ray Study
J. Chem. Soc., Chem. Commun. 1995, 2221-2222.

48) Nishiyama, H.; Itoh, Y.; Sugawara, Y.; Matsumoto, H.; Aoki, K.; Itoh, K.
Chiral Ruthenium(Ii)-Bis(2-Oxazolin-2-yl) Pyridine Complexes. Asymmetric Catalytic Cyclopropanation of Olefins and Diazoacetates
Bull. Chem. Soc. Jpn. 1995, 68, 1247-1262.

47) Nishiyama, H.; Park, S. B.; Itoh, K.
Formation of a Vinylcarbene Complex of Chiral [Bis(4-Isopropyloxazolin-2-yl)Pyridine]-Dichlororuthenium(II) from 3,3-Diphenylcyclopropene
Chem. Lett. 1995, 599-600.

46) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, S. B.; Itoh, K.
New Chiral Ruthenium Bis(Oxazolinyl)Pyridine Catalyst. Efficient Asymmetric Cyclopropanation of Olefins with Diazoacetates
J. Am. Chem. Soc. 1994, 116, 2223-2224.

45) Park, S. B.; Nishiyama, H.; Itoh, Y.; Itoh, K.
Trimethylsilylcarbene and Bis(Trimethylsilyl) Formaldehyde Azine Complexes of Chiral Bis(4-Isopropyloxazolinyl)Pyridine(Dichloro)Ruthenium(II)
J. Chem. Soc. Chem. Commun. 1994, 1315-1316.

44) Nishiyama, H.; Park, S. B.; Haga, M.; Aoki, K.; Itoh, K.
Ruthenium(II)Cl-2-Bis(Oxazolinyl)Bipyridine Complex - Its Structure and Reactivity
Chem. Lett. 1994, 1111-1114.

43) Nishiyama, H.; Tajima, T.; Takayama, M.; Itoh, K.
Chirality Recognition of 1,1'-Bi-2-Naphthol with Optically-Active Bis(Oxazolinyl)Pyridines
Tetrahedron-Asymmetry 1993, 4, 1461-1464.

42) Nagashima, H.; Ueda, T.; Nishiyama, H.; Itoh, K.
Dehydrogenative Silylation of Ketones with a Bifunctional Organosilane by Rhodium-Pybox Catalysts
Chem. Lett. 1993, 347-350.

41) Nishiyama, H.; Yamaguchi, S.; Park, S. B.; Itoh, K.
New Chiral Bis(Oxazolinyl)Bipyridine Ligand (Bipymox): Enantioselection in the Asymmetric Hydrosilylation of Ketones
Tetrahedron-Asymmetry 1993, 4, 143-150.

40) Nishiyama, H.; Yamaguchi, S.; Kondo, M.; Itoh, K.
Electronic Substituent Effect of Nitrogen Ligands in Catalytic Asymmetric Hydrosilylation of Ketones: Chiral 4-Substituted Bis(Oxazolinyl)Pyridines
J. Org. Chem. 1992, 57, 4306-4309.

39) Nishiyama, H.; Park, S. B.; Itoh, K.
Stereoselectivity in Hydrosilylative Reduction of Substituted Cyclohexanone Derivatives with Chiral Rhodium-Bis(Oxazolinyl)Pyridine Catalyst
Tetrahedron-Asymmetry 1992, 3, 1029-1034.

38) Nishiyama, H.; Isaka, K.; Itoh, K.; Ohno, K.; Nagase, H.; Matsumoto, K.; Yoshiwara, H.
Metal Halogen Exchange between Polybromoanisoles and Aliphatic Grignard-Reagents: A Synthesis of Cyclopenta[B]Benzofurans
J. Org. Chem. 1992, 57, 407-410.

37) Nishiyama, H.; Hirai, T.; Itoh, K.
Methylation of Bis(Oxazolinyl)Pyridinerhodium(III) Chlorides with Trimethylaluminum
J. Organomet. Chem. 1992, 431, 227-231.

36) Nishiyama, H.; Horihata, M.; Hirai, T.; Wakamatsu, S.; Itoh, K.
Oxidative-Addition Reactions of Alkyl Chlorides with Chlorobis(Cyclooctene)Rhodium(I) and the Bis(Oxazolinyl)Pyridine Ligand - Formation of Stable (Chloromethyl)Rhodium(III) Complexes and Their Reactions
Organometallics 1991, 10, 2706-2708.

35) Nishiyama, H.; Kondo, M.; Nakamura, T.; Itoh, K.
Highly Enantioselective Hydrosilylation of Ketones with Chiral and C2-Symmetrical Bis(Oxazolinyl)Pyridine-Rhodium Catalysts
Organometallics 1991, 10, 500-508.

34) Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K.
Chiral and C2-Symmetrical Bis(Oxazolinylpyridine)Rhodium(III) Complexes - Effective Catalysts for Asymmetric Hydrosilylation of Ketones
Organometallics 1989, 8, 846-848.

33) Nishiyama, H.; Sakuta, K.; Osaka, N.; Arai, H.; Matsumoto, M.; Itoh, K.
Silicon-Directed Beckmann Fragmentation
Tetrahedron 1988, 44, 2413-2426.

32) Nishiyama, H.; Matsumoto, M.; Arai, H.; Sakaguchi, H.; Itoh, K.
Silicon-Directed and Tin-Directed Oxidative Decarboxylation - Regioselective Formation of Olefins from Beta-Silyl and Beta-Stannyl Carboxylic-Acids
Tetrahedron Lett. 1986, 27, 1599-1602.

31) Nishiyama, H.; Arai, H.; Kanai, Y.; Kawashima, H.; Itoh, K.
Oxidative Cyclization of Beta-Stannyl Hydrazones
Tetrahedron Lett. 1986, 27, 361-364.

30) Nishiyama, H.; Arai, H.; Ohki, T.; Itoh, K.
Oxidative Fragmentation of Beta-Stannyl Oximes: Stereospecific Formation of Unsaturated Nitrile Oxides
J. Am. Chem. Soc. 1985, 107, 5310-5312.

29) Nishiyama, H.; Matsumoto, M.; Matsukura, T.; Miura, R.; Itoh, K.
A New Cyclopalladation Reaction Involving Facile Chelated Transmetalation: Selective Cleavage of C-Sn and C-Si Bonds of Stannyl and Silyl Ketoximes
Organometallics 1985, 4, 1911-1912.

28) Nishiyama, H.; Sakuta, K.; Itoh, K.
Conjugate Addition of Lithiotrimethylsilylacetate. A Simple Synthesis of Methyl Jasmonate Via Vicinal Double Alkylation
Tetrahedron Lett. 1984, 25, 2487-2488.

27) Nishiyama, H.; Kitajima, T.; Matsumoto, M.; Itoh, K.
Silylmethyl Radical Cyclization: New Stereoselective Method for 1,3-Diol Synthesis from Allylic Alcohols
J. Org. Chem. 1984, 49, 2298-2300.

26) Itoh, K.; Nishiyama, H.
A New Synthetic Method of Beta-Substituted Furans
Heterocycles 1984, 21, 449-449.

25) Nishiyama, H.; Sakuta, K.; Itoh, K.
New Stereocontrolled Approach to Some Insect Pheromones Via Silicon-Directed Beckmann Fragmentation
Tetrahedron Lett. 1984, 25, 223-226.

24) Itoh, K.; Nagashima, H.; Ohshima, T.; Oshima, N.; Nishiyama, H.
Bis(1-3-5-6-Eta-Cyclooctadienyl)Ruthenium - Preparation, Nmr-Spectroscopy, and Isomerization to (Eta-6-1,3,5-Cyclooctatriene)(1-2-5-6-Eta-1,5-Cyclooctadiene)Rutheniumvi a the Activation of a C-H Bond
J. Organomet. Chem. 1984, 272, 179-188.

23) Nishiyama, H.; Sakuta, K.; Osaka, N.; Itoh, K.
Silicon-Directed Beckmann Fragmentation - Catalytic Cleavage of Cyclic Beta-Trimethylsilylketoxime Acetates with Trimethylsilyl Trifluoromethanesulfonate
Tetrahedron Lett. 1983, 24, 4021-4024.

22) Nishiyama, H.; Naritomi, T.; Sakuta, K.; Itoh, K.
Silver-Induced Allylation of Beta-Bromo Ethers with Allylsilanes
J. Org. Chem. 1983, 48, 1557-1558.

21) Itoh, K.; Mukai, K.; Nagashima, H.; Nishiyama, H.
Selective [Pi-6s + Pi-2s] Cycloaddition of a Coordinated Cyclic Triene with Alkynes - Formation of Bicyclo(4.2.2]Decatriene Skeleton on a Ru(0) Template
Chem. Lett. 1983, 499-502.

20) Nishiyama, H.; Itagaki, K.; Osaka, N.; Itoh, K.
Transformation of Alpha-Phenylselenoketones to Allylic Selenides Via Migration of the Phenylseleno Group
Tetrahedron Lett. 1982, 23, 4103-4106.

19) Nishiyama, H.; Itoh, K.
Reaction of 2-Methoxyethyl Hemiacetals with Allylsilanes in the Presence of Titanium Tetrachloride - Regioselective C-O Bond-Cleavage of the Unsymmetrical Acetals
J. Org. Chem. 1982, 47, 2496-2498.

18) Nishiyama, H.; Yokoyama, H.; Narimatsu, S.; Itoh, K.
Preparation and Synthetic Application of 2-Bromoallyltrimethylsilane as a 1-Hydroxymethylvinyl Anion Equivalent
Tetrahedron Lett. 1982, 23, 1267-1270.

17) Nishiyama, H.; Kitajima, T.; Yamamoto, A.; Itoh, K.
New Rearrangement of Phenylselenoaldehydes and Trimethylsilylmethyl Groups in 2-Hydroxy-3-Trimethylsilylpropyl Selenides
J Chem. Soc., Chem. Commun.,
1982, 1232-1233.

16) Nishiyama, H.; Narimatsu, S.; Sakuta, K.; Itoh, K.
Reaction of Allylsilanes and Monothioacetals in the Presence of Lewis-Acids - Regioselectivity in the Cleavage of the Acetals
J Chem. Soc., Chem. Commun., 1982, 459-460.

15) Nishiyama, H.; Narimatsu, S.; Itoh, K.
Preparation and Synthetic Application of 3-Bromoallyltrimethylsilane as Hydroxypropenyl Synthons
Tetrahedron Lett. 1981, 22, 5289-5292.

14) Nishiyama, H.; Itagaki, K.; Sakuta, K.; Itoh, K.
Phenylselenodesilylation of Allylsilanes and Regiospecific Transformation of Allylsilanes to Allylic Alcohols Via Allylselenides
Tetrahedron Lett. 1981, 22, 5285-5288.

13) Nishiyama, H.; Itagaki, K.; Takahashi, K.; Itoh, K.
Regio-Selective and Stereo-Selective Alkylation of 3-Trimethylsilylmethyl Dienolates - a Novel Synthesis of 3-Alkylated 2-Methallylsilanes
Tetrahedron Lett. 1981, 22, 1691-1694.

12) Nishiyama, H.; Sasaki, M.; Itoh, K.
Efficient Transformation of (Z)-2-Butene-1,4-Diols to Substituted Furans with Pyridinium Chlorochromate (PCC)
Chem. Lett. 1981, 1363-1366.

11) Nishiyama, H.; Sasaki, M.; Itoh, K.
Stereoselective Addition of Readily Available Organocopper Reagents to Dimethyl Acetylenedicarboxylate
Chem. Lett. 1981, 905-908.

10) Itoh, K.; Hirai, K.; Sasaki, M.; Nakamura, Y.; Nishiyama, H.
Palladium Catalyzed Regioselective Cotrimerization between Dimethyl Acetylenedicarboxylate and 2 1-Alkene Molecules
Chem. Lett. 1981, 865-868.

<1974-1980>
9) Nishiyama, H.; Ohno, K.
Synthesis of Prostaglandins and Their Congeners .5. Synthesis of 6,7-Didehydro-5-Hydroxy and 4,5-Didehydro-6-Hydroxyprostaglandin-F1-Alpha - Photosensitized Oxygenation of Prostaglandin-F2-Alpha
Chem. Lett. 1979, 661-664.

8) Ohno, K.; Nishiyama, H.
Synthesis of Prostaglandins and Their Congeners .6. 4,5,6,7-Tetradehydro-Pgi1, a Stable and Potent Inhibitor of Blood-Platelet Aggregation
Tetrahedron Lett. 1979, 3003-3004.

7) Nishiyama, H.; Ohno, K.
Synthesis of Prostaglandins and Their Congeners .7. Synthesis of 6,7-Dehydro-5-Oxo-Prostaglandin-I1 - Stable Analog of Prostacyclin
Tetrahedron Lett. 1979, 3481-3484.

6) Ohno, K.; Nishiyama, H.; Nagase, H.
Mild Methylation of Alcohols with Diazomethane Catalyzed by Silica-Gel
Tetrahedron Lett. 1979, 4405-4406.

5) Nishiyama, H.; Nagase, H.; Ohno, K.
Reaction of Some Amides and Thioamides with Diazomethane Catalyzed by Silica-Gel
Tetrahedron Lett. 1979, 4671-4674.

4) Nishiyama, H.
Preparation of Sulfonium-Eta-3-Allylide Complexes of Palladium(II)
J. Organomet. Chem. 1979, 165, 407-413.

3) Pierpont, C. G.; Downs, H. H.; Itoh, K.; Nishiyama, H.; Ishii, Y.
Synthesis and Structure of Triphenylphosphonium Cyclopentadienylide Adduct of Oligomeric Tetrakis(Methoxycarbonyl)Palladiacyclopentadiene
J. Organomet. Chem. 1977, 124, 93-101.

2) Nishiyama, H.; Itoh, K.; Ishii, Y.
Convenient Synthesis and Structure of Stabilized Ylide Complexes of Palladium(II)
J. Organomet. Chem. 1975, 87, 129-135.

1) Itoh, K.; Nishiyam.H; Ohnishi, T.; Ishii, Y.
Simple Preparation of Pi-Allylphosphonium Ylide Complexes of Palladium (II)
J. Organomet. Chem. 1974, 76, 401-406.