Ito paper of Nishi Lab

発表論文:

(42) Ito, J.; Ubukata, S.; Muraoka, S.; Nishiyama, H. "Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes", Chem. Eur. J. in press.

(41) Ito, J.; Sugino, K.; Matsushima, S.; Sakaguchi, H.; Iwata, H.; Ishihara, T.; Nishiyama, H. "Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction", Organometallics 2016, 35, 1885-1894.

(40) Naganawa, Y.; Kawagishi, M.; Ito, J.; Nishiyama, H. "Asymmetric Induction at Remote All-carbon Quaternary Centers of Cyclohexadienones by Rh-catalyzed Conjugate Hydrosilylation" Angew. Chem. Int. Ed. 2016, 55, 6873-6876.

(39) Ubukata, S.; Ito, J.; Oguri, R.; Nishiyama, H. "Asymmetric Three Component Coupling Reaction of Alkyne, Enone, and Aldehyde Catalyzed by Chiral Phebox Ruthenium Catalysts" J. Org. Chem. 2016, 81, 3347-3355.

(38) Ito, J.; Miyakawa, T.; Nishiyama, H. "Asymmetric β-Functionalization of Secondary Amine with CH2Cl2 on a Chiral NCN Pincer Rh Complex", J. Organomet. Chem. 2015, 794, 318-322.

(37) Ito, J.; Hosokawa, S.; Hairuzana B. K.; Nishiyama, H. "Preparation, Characterization, and Catalytic Reactions of NCN Pincer Iron Complexes Containing Stannyl, Silyl, Methyl, and Phenyl Ligands", Organometallics 2015, 34, 1377-1383

(36) Ito, J.; Crestani, M. G.; Bailey, B. C.; Gao, X.; Mindiola, D. J.
N?N bond cleavage in diazoalkanes with a titanium alkylidene
Polyhedron 2014, 84, 177-181 (doi:10.1016/j.poly.2014.07.036, Available online 1 August 2014)

(35) Crestani, M. G.; Hickey, A. K.; Gao, X.; Pinter, B.; Cavaliere, V. N.; Ito, J.; Chen, C.-H.; Mindiola, D. J.
Room Temperature Dehydrogenation of Ethane, Propane, Linear Alkanes C4-C8, and Some Cyclic Alkanes by Titanium-Carbon Multiple Bonds
J. Am. Chem. Soc. 2013, 135, 14754-14767

(34) Hosokawa, S.; Ito, J.; Nishiyama
NCN-Pincer Cobalt Complexes Containing Bis(oxazolinyl)phenyl Ligands
Organometallics 2013, 32, 3980-3985.

(33) Ito, J.; Fujii, K.; Nishiyama, H.
Direct Conjugate Addition of Alkynes with a,b-Unsaturated Carbonyl Compounds Catalyzed by NCN Pincer Ru Complexes
Chem. Eur. J, .2013, 19, 601-605.

(32) Itoh, K.; Tsuruta, A.; Ito, J.; Yamamoto, Y.; Nishiyama, H.
Enantioselective Synthesis of Optically Active 3,3-Diarylpropanoates by Conjugate Hydrosilylation with Chiral Rh-bis(oxazolinyl)phenyl Catalysts
J. Org. Chem. 2012, 77, 10914-10919.

(31) Hosokawa, S.; Ito, J.; Nishiyama, H.
Change in Coordination of NCN Pincer Iron Complexes Containing Bis(oxazolinyl)phenyl Ligands
Organometallics, 2012, 31, 8283-8290

(30) Naito, T.; Yoneda, T.; Ito, J.; Nishiyama, H.
Enantioselective Hydrosilylation of Aromatic Alkenes Catalyzed by Chiral Bis(oxazolinyl)phenyl Rhodium Acetate Complexes
Synlett, 2012, 23, 2957-2960.

(29) Ito, J.; Kaneda, T.; Nishiyama, H. "Intermolecular C?H Bond Activation of Alkanes and Arenes by NCN Pincer Iridium(III) Acetate Complexes Containing Bis(oxazolinyl)phenyl Ligands", Organometallics 2012, 31, 4442-4449.

(28) Ito, J.; Teshima, T.; Nishiyama, H.
Enhancement of Enantioselectivity by Alcohol Additives in Asymmetric Hydrogenation with Bis(oxazolinyl)phenyl Ruthenium Catalysts
Chem. Commun. 2012, 48, 1105-1107.

(27) Klare, H. F. T.; Oestreich, M.; Ito, J.; Nishiyama, H.; Ohki, Y.; Tatsumi, K.
Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
J. Am. Chem. Soc. 2011, 133, 3312-33115. (February 22)

(26) Hosokawa, S.; Ito, J.; Nishiyama, H.
A Chiral Iron Complex Containing a Bis(oxazolinyl)phenyl Ligand: Preparation and Asymmetric Hydrosilylation of Ketones
Organometallics 2010, 29, 5773-5775

(25) Inagaki, T.; Ito, A.; Ito, J.; Nishiyama, H.
Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration
Angew. Chem. Int. Ed. 2010, 49, 9384-9387

(24) Ito, J.; Asai, R.; Nishiyama, H.
Asymmetric Direct Alkynylation Catalyzed by Chiral Ru-Bis(oxazolinyl)phenyl Complexes
Org. Lett. 2010, 12, 3860-3862.

(23) Ito, J.; Ujiie, S.; Nishiyama, H.
Chiral Bis(oxazolinyl)phenyl Ru(II) Catalysts for Highly Enantioselective Cyclopropanation
Chem. Eur. J. 2010, 16, 4986-4990 (Communication)

(22) Inagaki, T.; Le, T. P.; Furuta, A.; Ito, J.; Nishiyama, H.
Iron- and Cobalt Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands
Chem. Eur. J., 2010, 16, 3090-3096 (Full Paper)

(21) Shiomi, T.; Adachi, T.; Ito, J.; Nishiyama, H.*
Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Chiral Rh(Phebox) Catalysts
Org. Lett. 2009, 11, 1011-1014

(20) Ito, J.; Ujiie, S.; Nishiyama, H.
New Bis(oxazolinyl)phenyl-Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones
Organometallics 2009, 28, 630-638

(19) Inagaki, T.; Yamada, Y.; Phong, L. T.; Furuta, A.; Ito, J.; Nishiyama, H.
Catalytic Hydrosilylation of Carbonyl Compounds with Zinc(II) Acetate: Asymmetric Induction Collaborated with N2S2 Ligands
Synlett 2009, 253-256

(18) Hashimoto, T.; Ito, J.; Nishiyama, H.
Felkin-Anh Selectivity in Rh(bisoxazolinylphenyl) Catalyzed Reductive Aldol Coupling Reaction. Asymmetric Synthesis of Stereotriads
Tetrahedron 2008, 64, 9408-9412

(17) Ito, J.; Miyakawa, T.; Nishiyama, H.
Amine-assisted C-Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Organometallics 2008, 27, 3312-3315

(16) Inoue, H.; Ito, J.; Kikuchi, M.; Nishiyama, H.
Asymmetric Ligand Exchange Reaction on Biphenol Derivatives and Chiral Bis(oxazolinyl)phenyl-Rhodium Complex
Chem. Asian J. 2008, 3, 1284.

(15) Ito, J.; Ohki, Y.; Iwata, M.; Tatsumi, K.
Trithio-Chloro Molybdate [MoClS 3]-: A Versatile Precursor for Molybdenum Trisulfido Complexes
Inrog. Chem. 2008, 47, 3763-3771.

(14) Ito, J.; Ujiie, S.; Nishiyama, H.
A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones
Chem. Commun. 2008, 1923-1925.

(13) Inoue, H.; Kikuchi, M.; Ito, J.; Nishiyama, H.
Chiral Phebox-Rhodium Complexes as Catalysts for Asymmetric Direct Aldol Reaction
Tetrahedron 2008, 64, 493-499.

(12) Hashimoto. T; Shiomi, T.; Ito, J.; Nishiyama, H.*
Asymmetric synthesis of a-chiral dihydrocinnamates by catalytic reductive aldol coupling and subsequent dehydroxylation
Tetrahedron 2007, 63, 12883-12887.

(11) Ito, J.; Kitase, M.; Nishiyama, H.*
Cross-Coupling of Alkynes Catalyzed by Phebox-rhodium Acetate Complexes
Organometallics 2007, 26, 6412-6417.

(10) Iizuka, Y.; Zhaoming, L.; Satoh, K.; Kamigaito, M.; Okamoto, Y.; Ito, J.; Nishiyama, H.
Chiral (-)-Diop Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reactions
Eur. J. Org. Chem. 2007, 782-791.

(9) Ito, J.; Nishiyama, H.
Carbon-Hydrogen Bond Activation of Arenes by a [Bis(oxazolinyl)phenyl]-rhodium(III) Acetate Complex
Eur. J. Inorg. Chem. 2007, 1114-1119.

(8) Uchimura, H.; Ito, J.; Iwasa, S.; Nishiyama, H.
Oxidative addition reactions and stereochemistry on rhodium/4,5-bis(2-oxazolinyl)xanthene complexes
J. Organomet. Chem. 2007, 692, 481-486.

(7) Ito, J.; Miyakawa, T.; Nishiyama, H.
A Carbon-Carbon Bond Formation on Bis(oxazolinyl)phenyl-Rhodium Complex in Reduction and Oxidative Addition Sequence
Organometallics 2006, 25, 5216-5218

(6) Shiomi, T.; Ito, J.; Yamamoto, Y.; Nishiyama, H.
4-Substituted-Phenyl(bisoxazoline)-Rhodium Complexes: Efficiency for Catalytic Asymmetric Reductive Aldol Reaction
Eur. J. Org. Chem. 2006, 5594-5600.

(5) Ito, J.; Shiomi, T.; Nishiyama, H.
Efficient Preparation of New Rhodium- and Iridium-[bis(oxazolinyl)-3,5-dimethylphenyl] Complexes by C-H Bond Activation. An Application in Asymmetric Synthesis
Adv. Synth. Catal. 2006, 348, 1235-1240.

(4) Ito, J.; Shima, T.; Suzuki, H.
Synthesis of Group 8-Group 6 Heterotrimetallic Polyhydrido Complexes Having Only a C5Me5 Group as Auxiliary Ligand
Organometallics 2006, 25, 1333-1336.

(3) Kanazawa, Y; Tsuchiya, Y.; Kobayashi, K.; Shiomi, T.; Itoh, J.-I.; Kikuchi, M.; Yamamoto, Y.; Nishiyama, H.
Asymmetric Conjugate Reduction of α,β-Unsaturated Ketones and Esters with Chiral Rhodium(2,6-bisoxazolinylphenyl) Catalysts
Chem. Eur. J. 2006, 12, 63-71.

(2) Ito, J.; Shima, T.; Suzuki, H.
Di- and Trinuclear Polyhydride Complexes Containing Ruthenium and Rhenium. Synthesis, Site Exchange, and H/D Exchange of Hydride Ligands
Organometallics 2004, 23, 2447-2460.

(1) Shima, T.; Ito, J. Suzuki, H.
Synthesis, Characterization, and Structure Determination of the Heterobimetallic Polyhydride Complexes (C5Me5)Ru(m-H)3MH3(C5Me5) (M = Mo, W) Containing
Group VI and Group VIII Metals
Organometallics
2001, 20, 10-12.

総説・著書など

Ito, J.; Nishiyama, H.
Ruthenium, [2,6-bis[4,5-dihydro-4-(1-methylethyl)-2-oxazolyl-κN3]pyridine-κN]dichloro(η2-ethene)-, stereoisomer
e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley Online Library (2014)

[Digest] Ito, J.; Nishiyama, H.
Recent Topics of Transfer Hydrogenation
Tetrahedron Lett. 2014, 55, 3133-3146.

[Book Chapters] Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multipotent Catalysts, J. Ito, H. Nishiyama, In "Organometallic Pincer Chemistry" Eds. G. van Koten, D. Milstein, Springer- Verlag, Berline/Heidelberg, Top. Organomet. Chem. 2013, 40, 243-270.

[総合論文]
伊藤淳一、西山久雄
光学活性ビス(オキサゾリニル)フェニル金属錯体を用いる不斉触媒反応
有機合成化学協会誌, 2013, 71, 791-803.
Asymmetric Catalysis Mediated by Optically Active Bis(oxazolinyl)phenyl Metal Complexes, J. Synth. Org. Chem. Jpn. 2013, 71, 791-803.

[Account] Ito, J.; Nishiyama, H.
Synthetic Utility of Chiral Bis(oxazolinyl)phenyl Transition-Metal Complexes
Synlett 2012, 23, 509-523.

[Book Chapters] Bifunctional Phebox Complexes for Asymmetric Catalysis, J. Ito, H. Nishiyama, In "Bifunctional Molecular Catalysis". Eds. T. Ikariya.; M. Shibasaki; Springer-Verlag, Berlin/Heidelberg, Top. Organomet. Chem. 2011, 37, 185-205.

[Account] Nishiyama,H.; Ito, J.
Bis(oxazolinyl)phenyl Transition-metal Complexes: Asymmetric Catalysis and Some Reactions of the Metals
Chem. Commun. 2010, 46, 203-212.

[Account] Nishiyama, H.;* Ito, J.; Shiomi, T.; Hashimoto, T.; Miyakawa, T.; Kitase, M.
Chiral phenyl-bis(oxazoline) as an efficient auxiliary for asymmetric catalysis
Pure Appl. Chem. 2008, 80, 743-749.

[Account] Nishiyama, H.; Ito, J.
Bis(oxazolinyl)phenyl Transition Metal Complexes: Synthesis, Asymmetric Catalysis, and Coordination Chemistry
Chem. Rec. 2007, 7, 159-166.

特許

ルテニウム化合物及びそれを用いた不斉シクロプロパン化合物の製造方法
出願人 国立大学法人名古屋大学 
発明者 西山 久雄、伊藤 淳一
出願番号 特願2010-043204 出願日2010-02-26
公開番号 特開2011-178699 公開日2011-09-15

講演など

第101触媒討論会(平成24年9月24〜26日、九州大学伊都キャンパス)
1I04 (依頼講演) 光学活性NCN ピンサー型配位子を有するRu、Fe 錯体の合成と触媒反応
伊藤 淳一

International Symposium on Organometallic Chemistry (ISOMC 2011) (November 11-12, 2011, Osaka University)
O3 Chiral Bis(oxazolinyl)phenyl Ruthenium and Iron Complexes for Asymmetric Catalytic Reactions (Invited Lecture)
Jun-ichi Ito

東海化学工業会受賞記念講演会(平成23年5月18日、名古屋市工業研究所)
「高性能オキサゾリン・ルテニウム触媒の設計と不斉合成への展開」 
伊藤 淳一

Pre-Symposium on Organometallic Chemisty (July 18, 2010, National Taiwan University, Taiwan)
II-9 Asymmetric Catalytic Reactions with Chiral Ru-bis(oxazolinyl)phenyl Complexes(招待講演)
Hisao Nishiyma, Jun-ichi Ito

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