Publication of Nishi Lab

2016
Jun-ichi Ito, Shino Ubukata; Shun Muraoka; Hisao Nishiyama, "Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes",Chem. Eur. J. in press.
Y. Naganawa, T. Aoyama, K. Kato, H. Nishiyama, "Cu(II)-catalyzed Enantioselective α-Hydroxylation and α-Chlorination of β-Ketoesters with N,N,O-Tridentate Chiral Phenanthroline Ligand",ChemistrySelect,2016,1,1938-1942.DOI: 10.1002/slct.201600449
Jun-ichi Ito, Kanae Sugino, Satoru Matsushima, Hiroki Sakaguchi, Hiroshi Iwata, Takahiro Ishihara, Hisao Nishiyama, "Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction",Organometallics2016,35,1885-1894.DOI: 10.1021/acs.organomet.6b00239(May 03, 2016)
Yuki Naganawa, Hiroki Abe, Hisao Nishiyama, "Ni(II)-catalyzed Asymmetric Michael Addition of Oxindoles with Modified N,N,O-Tridentate Chiral Phenanthroline Ligands",Synlett2016, 1973-1978.DOI: 10.1055/s-0035-1561630(August 2016)
Ubukata, Shino; Ito, Jun-Ichi; Oguri, Ryota; Nishiyama, Hisao, "Asymmetric Three Component Coupling Reaction of Alkyne, Enone, and Aldehyde Catalyzed by Chiral Phebox Ruthenium Catalysts"J. Org. Chem.2016,81,3347-3355.DOI: 10.1021/acs.joc.6b00374(March 23, 2016)
Yuki Naganawa,* Mayu Kawagishi, Jun-ichi Ito, and Hisao Nishiyama* "Asymmetric Induction at Remote All-carbon Quaternary Centers of Cyclohexadienones by Rh-catalyzed Conjugate Hydrosilylation"Angew. Chem. Int. Ed.2016,55, 6873-6876. (DOI:10.1002/anie.201601636)
2015
Naganawa, Y.; Aoyama, T.; Nishiyama, H. "Cu(II)-catalyzed enantioselective oxygen atom transfer from oxaziridine to oxindole derivatives with chiral phenanthroline",Org. Biomol. Chem.2015,13, 11499-11506 (DOI: 10.1039/C5OB01840D, 02 Oct 2015)2015 Hot Articles
Naganawa, Y.; Komatsu, H.; Nishiyama, H. "Zinc-catalyzed Enantioselective Electrophilic Amination of β-Ketocarbonyl Compounds with Axially Chiral Phenanthroline Ligands",Chem. Lett.2015,44, 1652-1654. (DOI: 10.1246/cl.150802, Sep 19, 2015)
Ito, J.; Miyakawa, T.; Nishiyama, H. "Asymmetric β-Functionalization of Secondary Amine with CH2Cl2 on a Chiral NCN Pincer Rh Complex",J. Organomet. Chem.2015,794,318-322. (doi:10.1016/j.jorganchem.2015.07.03, 31 Jul 2015).
Naganawa, Y.; Namba, T.; Kawagishi, M.; Nishiyama, H. "Construction of Chiral Silicon Center via Rh-Catalyzed Enantioselective Intramolecular Hydrosilylation",Chem. Eur. J.2015,21, 9319-9322. (DOI: 10.1002/chem.201501568, 28 May 2015)
Toribatake, K.; Miyata, S.; Naganawa, Y.; Nishiyama H. "Asymmetric synthesis of optically active 3-amino-1,2-diols from N-acyl-protected allylamines via catalytic diboration with Rh[bis(oxazolinyl)phenyl] catalysts",Tetrahedron.2015,71,3203-3208. (doi:10.1016/j.tet.2015.04.011, May 21, 2015).
Ito, J.; Hosokawa, S.; Hairuzana B. K.; Nishiyama, H. "Preparation, Characterization, and Catalytic Reactions of NCN Pincer Iron Complexes Containing Stannyl, Silyl, Methyl, and Phenyl Ligands",Organometallics2015,34, 1377-1383 (DOI: 10.1021/acs.organomet.5b00082, April 1, 2015).
2014
Naganawa, Y.; Namba, T.; Aoyama, T.; Shoji, K.; Nishiyama, H. "Design of novel chiral N,N,O-tridentate phenanthroline ligands and its application to enantioselective addition of organozinc reagents to aldehydes",Chem. Commun.,2014,50, 13224-13227 (DOI: 10.1039/C4CC05020G, 25 Jul 2014) [Inside back cover]
2013
Toribatake, K.; Nishiyama, H. "Asymmetric diboration of terminal alkenes with rhodium catalyst and subsequent oxidation: Enantioselective synthesis of optically active 1,2-diols",Angew. Chem. Int. Ed.2013,52, 11011-11015 (DOI: 10.1002/anie.201305181, Sep 2, 2013)
Hosokawa, S.; Ito, J.; Nishiyama, "NCN-Pincer Cobalt Complexes Containing Bis(oxazolinyl)phenyl Ligands",Organometallics2013,32, 3980-3985 (DOI: 10.1021/om400450n, July 1, 2013)
Toribatake, K.; Zhou, L.; Tsuruta, A.; Nishiyama, H. "Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalyst",Tetrahedron,2013,69,3551-3560 (DOI: 10.1016/j.tet.2013.02.086, April 29, 2013)
Ito, J.; Fujii, K.; Nishiyama, H. "Direct Conjugate Addition of Alkynes witha,b-Unsaturated Carbonyl Compounds Catalyzed by NCN Pincer Ru Complexes",Chem. Eur. J.,2013,19, 601-605. (DOI: 10.1002/chem.201203380, NOV 23, 2012)
2012
Itoh, K.; Tsuruta, A.; Ito, J.; Yamamoto, Y.; Nishiyama, H. "Enantioselective Synthesis of Optically Active 3,3-Diarylpropanoates by Conjugate Hydrosilylation with Chiral Rh-bis(oxazolinyl)phenyl Catalysts"J. Org. Chem.2012,77, 10914-10919. (DOI: 10.1021/jo302357b, Nov. 10, 2012)
Hosokawa, S.; Ito, J.; Nishiyama, H. "Change in Coordination of NCN Pincer Iron Complexes Containing Bis(oxazolinyl)phenyl Ligands",Organometallics,2012,31, 8283-8290. (DOI: 10.1021/om300901k, Nov 12, 2012)
Naito, T.; Yoneda, T.; Ito, J.; Nishiyama, H. "Enantioselective Hydrosilylation of Aromatic Alkenes Catalyzed by Chiral Bis(oxazolinyl)phenyl Rhodium Acetate Complexes",Synlett,2012,23, 2957-2960 (DOI: 10.1055/s-0032-1317677, December 2012)
Yamamoto, Y.; Fukatsu, K.; Nishiyama, H. "Ruthenium-catalyzed hydrophosphinylative cyclization of 1,6-diynes. Stereoselective synthesis of exocyclic 1,3-dienylphosphine oxides",Chem. Commun.,2012,48, 7985-7987 (DOI: 10.1039/C2CC34044E, Jun 22, 2012)
Yamashita, K.; Yamamoto, Y.; Nishiyama, H. "Ruthenium-Catalyzed Transfer Oxygenative Cyclization of α,ω-Diynes: Unprecedented [2 + 2 + 1] Route to Bicyclic Furans via Ruthenacyclopentatriene",J. Am. Chem. Soc.2012,134, 7660-7663 (DOI: 10.1021/ja302868s, April 20, 2012)
Ito, J.; Kaneda, T.; Nishiyama, H. "Intermolecular C?H Bond Activation of Alkanes and Arenes by NCN Pincer Iridium(III) Acetate Complexes Containing Bis(oxazolinyl)phenyl Ligands",Organometallics2012,31, 4442-4449 (DOI: 10.1021/om3002137).
Yamamoto, Y.; Yamada, S.; Nishiyama, H. "Copper-Catalyzed Regio- and Stereoselective Conjugate Allylation of Electron-Deficient Alkynes with Allylboronates under Mild Conditions",Chem. Eur. J.2012,18, 3153-3156.(DOI: 10.1002/chem.201103697, Feb 16, 2012)
[Account] Ito, J.; Nishiyama, H. "Synthetic Utility of Chiral Bis(oxazolinyl)phenyl Transition-Metal Complexes",Synlett2012,23, 509-523 (DOI: 10.1055/s-0031-1290315)
Ito, J.; Teshima, T.; Nishiyama, H. "Enhancement of Enantioselectivity by Alcohol Additives in Asymmetric Hydrogenation with Bis(oxazolinyl)phenyl Ruthenium Catalysts",Chem. Commun.2012,48, 1105-1107 (DOI: 10.1039/C1CC16057E, Nov 14, 2011).
2011
Yamashita, K.; Nagashima, Y.; Yamamoto, Y.; Nishiyama, H. "Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activation via metallacyclopentatriene",Chem. Commun.2011,47, 11552-11554 (DOI: 10.1039/C1CC13744A, Sep 19, 2011)
Motoyama, Y.; Sakakura, T.; Takemoto, T.; Shimozono, K.; Aoki, K.; Nishiyama, H. "Enantioselective Addition of Allyltin Reagents to Amino Aldehydes Catalyzed with Bis(oxazolinyl)phenylrhodium(III) Aqua Complexes",Molecules2011,16, 5387-5401(DOI: 10.3390/molecules16075387)
Ohshima,T.*; Kawabata, T.; Takeuchi, Y,; Kakinuma, T.; Iwasaki, T.; Yonezawa, T.; Murakami, H.; Nishiyama, H.; Mashima, K.*, "C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of a-Ketoesters",Angew. Chem. Int. Ed.,2011,50, 6296-6300. (DOI: 10.1002/anie.201100252, May 30, 2011)
Yamamoto, Y.; Yamada, S.; Nishiyama, H. "Synthesis of 3-Arylindole-2-carboxylates via Copper-Catalyzed Hydroarylation of o-Nitrophenyl-Substituted Alkynoates and Subsequent Cadogan Cyclization",Adv. Synth. Catal.2011,353, 701-706. (DOI: 10.1002/adsc.201000858, March 15, 2011)
Klare, H. F. T.; Oestreich, M.; Ito, J.; Nishiyama, H.; Ohki, Y.; Tatsumi, K., "Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism",J. Am. Chem. Soc.2011,133,3312-3315. (DOI: 10.1021/ja111483r, February 22, 2011)
Yamamoto, Y.; Yamashita, K.; Nishiyama, H. "Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynes",Chem. Commun.2011,47, 1556-1558. (DOI: 10.1039/C0CC04345A, Nov 29, 2011)
2010
Hosokawa, S.; Ito, J.; Nishiyama, H. "A Chiral Iron Complex Containing a Bis(oxazolinyl)phenyl Ligand: Preparation and Asymmetric Hydrosilylation of Ketones",Organometallics2010,29, 5773-5775. (DOI: 10.1021/om1009186, October 27, 2010)
Inagaki, T.; Ito, A.; Ito, J.; Nishiyama, H. "Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration",Angew. Chem. Int. Ed.2010,49, 9384-9387. (DOI: 10.1002/anie.201005363, Nov 4, 2010)
Selected as "Hot papers"
Ito, J.; Asai, R.; Nishiyama, H. "Asymmetric Direct Alkynylation Catalyzed by Chiral Ru-Bis(oxazolinyl)phenyl Complexes",Org. Lett.2010,12, 3860-3862. (DOI: 10.1021/ol1015338, August 10, 2010)
Ito, J.; Ujiie, S.; Nishiyama, H. "Chiral Bis(oxazolinyl)phenyl Ru(II) Catalysts for Highly Enantioselective Cyclopropanation",Chem. Eur. J.2010,16, 4986-4990 (Communication) (DOI: 10.1002/chem.200903514, Mar 25, 2010)
Inagaki, T.; Le, T. P.; Furuta, A.; Ito, J.; Nishiyama, H. "Iron- and Cobalt Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands",Chem. Eur. J.,2010,16, 3090-3096 (Full Paper) (DOI: 10.1002/chem.200903118, Jan 29, 2010)
[Feature Article] Nishiyama,H.; Ito, J. "Bis(oxazolinyl)phenyl Transition-metal Complexes: Asymmetric Catalysis and Some Reactions of the Metals",Chem. Commun.2010,46, 203-212 (DOI: 10.1039/B918923H, Nov 19, 2009)
2009-2004