Nishiyama account of Nishi Lab

総説

Y. Naganawa, H. Nishiyama
Renovation of Optically Active Phenanthroline as Powerful Chiral Ligands for Versatile Asymmetric Metal Catalysis
Chem. Rec. in press.

西山久雄
使ってもらえる光学活性窒素配位子の開発
有機合成化学協会誌、2015年、第73巻、925−931頁(ラウンジ)

Hisao Nishiyama
Usable optically active nitrogen-based tridentate ligands for asymmetric catalysis
J. Synth. Org. Chem. Jpn., 2015, 73, 925-931. (Lounge)

Nishiyama, H.
Bis(acetato)aqua[2,6-bis[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-phenyl]rhodium
e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley Online Library (2014)

Ito, J.; Nishiyama, H.
Ruthenium, [2,6-bis[4,5-dihydro-4-(1-methylethyl)-2-oxazolyl-κN3]pyridine-κN]dichloro(η2-ethene)-, stereoisomer
e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley Online Library (2014)

[Digest] Ito, J.; Nishiyama, H.
Recent Topics of Transfer Hydrogenation
Tetrahedron Lett. 2014, 55, 3133-3146.

[Account] Ito, J.; Nishiyama, H.
Asymmetric Catalysis Mediated by Optically Active Bis(oxazolinyl)phenyl Metal Complexes
J. Synth. Org. Chem. Jpn. 2013, 71, 791-803.

[Account] Ito, J.; Nishiyama, H.
Synthetic Utility of Chiral Bis(oxazolinyl)phenyl Transition-Metal Complexes
Synlett 2012, 23, 509-523
synlett2012.tif

[Feature Article] Nishiyama,H.; Ito, J.
Bis(oxazolinyl)phenyl Transition-metal Complexes: Asymmetric Catalysis and Some Reactions of the Metals
Chem. Commun. 2010, 46, 203-212
CC2010.gif

[Account] Nishiyama, H.; Ito, J.; Shiomi, T.; Hashimoto, T.; Miyakawa, T.; Kitase, M.
Chiral phenyl-bis(oxazoline) as an efficient auxiliary for asymmetric catalysis
Pure Appl. Chem. 2008, 80, 743-749.

[Account] Nishiyama, H.
Synthesis and use of bisoxazolinyl-phenyl pincers
Chem. Soc. Rev. 2007, 36, 1133-1141.

[Account] Nishiyama, H.; Ito, J.
Bis(oxazolinyl)phenyl Transition Metal Complexes: Synthesis, Asymmetric Catalysis, and Coordination Chemistry
Chem. Rec. 2007, 7, 159-166.

[Review] Iwasa, S.; Fakhruddin, A.; Nishiyama, H.
Synthesis of acylnitroso intermediates and their synthetic applications
Mini-Reviews in Organic Chemistry 2005, 2, 157-175.

[Account] Motoyama, Y.; Nishiyama, H.
Chiral transition metal Lewis acids bearing bis(oxazolinyl)phenyl (Phebox) as a pincer ligand: Synthesis and application for the asymmetric reactions
J. Synth. Org. Chem. Jpn. 2003, 61, 343-351.

[Account] Motoyama, Y.; Nishiyama, H.
Asymmetric Reactions with Chiral Bis(oxazolinyl)phenyl-Rh, -Pt, and -Pd Complexes and Their Lewi Acid Activity in "Latest Frontiers of Organic Synthesis", Ed. Y. Kobayashi, Research Signpost, India, 2002, pp 1-24.

[Account] Nagase, H.; Matsumoto, K.; Nishiyama, H.
Synthetic study of a new class of stable PGI(2) analogue, m-phenylene PGI(2) - Synthesis of beraprost sodium
J. Synth. Org. Chem. Jpn. 1996, 54, 1055-1066.

[Account] Nishiyama, H.; Itoh, K.
Optically-Active Bis(Oxazolinyl)Pyridine (Pybox) Rhodium Complexes - Asymmetric Hydrosilylation of Ketones
J. Synth. Org. Chem. Jpn. 1995, 53, 500-508.

[Account] Nishiyama, H.; Itoh, K.
Synthetic Applications of Allylsilanes as Synthons of Several Allylic Alcohols
J. Synth. Org. Chem. Jpn. 1982, 40, 518-524.

著書・記事

J. Ito, H. Nishiyama, Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multipotent Catalysts, In "Organometallic Pincer Chemistry" Eds. G. van Koten, D. Milstein, Springer- Verlag, Berline/Heidelberg, Top. Organomet. Chem. 2013, 40, 243-270

H. Nishiyama, Hydrosilylation, In "Comprehensive Chirality", Eds. H. Yamamoto, E. M. Carreira, Elsevire Science, 2012, Volume 5, Chapter 5.15, pp 318-333

J. Ito, H. Nishiyama, Bifunctional Phebox Complexes for Asymmetric Catalysis, In "Bifunctional Molecular Catalysis". Eds. T. Ikariya.; M. Shibasaki; Springer-Verlag, Berlin/Heidelberg, Top. Organomet. Chem. 2011, 37, 185-205

西山久雄、「ビスオキサゾリン鉄触媒」、特集「鉄触媒のルネサンス」、化学と工業(日本化学会、Vo.63-8;平成22年8月1日発行)(p 642)および表紙(右下)Fe(BOPA)Cl2錯体

S. Iwasa; H. Nishiyama, Transition-Metal Lewis Acids: From Vanadium to Platinum, In "Acid Catalysis in Modern Organic Synthesis". Eds. Yamamoto, H.; Ishihara, K.; 2008, Wiley-VCH Verlag GmbH & Co. KGaA,Weinheim, Chapter 16, pp 859-901

H. Nishiyama, T. Shiomi, Reductive Aldol, Michael, and Mannich Reactions, in "Top. Curr. Chem.: Metal Catalyzed Reductive C-C Bond Formation", Ed. M. J. Krische, Springer-Verlag, Berlin/Heidelberg, 2007, 279, 105-137.

西山久雄,銅ヒドリド種を用いる実用的な触媒的不斉共役還元反応,化学,60 (5),72-73 (2005).

西山久雄,還元反応,不斉還元へつながる基本反応,実力養成化学スクール「有機合成化学」第3章,大嶌幸一郎編集,日本化学会編,丸善,pp 53-73 (2005).

H. Nishiyama, Ruthenium-Catalyzed Cyclopropanation, In Ruthenium in Organic Synthesis (Ed. S.-I. Murahashi), Wiley-VCH Verlag, Weinheim, 2004, Chap. 7, pp 179-187.

H. Nishiyama, Hydrosilylation of Carbonyl and Imine Compounds, In Transition Metals for Organic Synthesis (Eds. M. Beller, C. Bolm), Wiley-VCH Verlag, Weinheim, 2004, pp 182-191.

西山久雄,67. カルベンの付加環化反応と挿入反応,有機合成のための触媒反応103(檜山爲次郎,野崎京子 編),東京化学同人,2004,pp 134-135.

西山久雄,66. 金属触媒によるシクロプロパン化,有機合成のための触媒反応103(檜山爲次郎,野崎京子 編),東京化学同人,2004,pp 132-133.

西山久雄,9. 不斉ヒドロシリル化反応,日本化学会編 第5版実験化学講座19,有機化合物の合成VII,不斉合成・ラジカル反応,丸善,2004,pp 131-138.

西山久雄,ジアゾカルボニル化合物の触媒反応,日本化学会編 第5版実験化学講座18,有機化合物の合成VI,金属を用いる有機合成,丸善,2004,pp 421-426.

H. Nishiyama, Cyclopropanation with Ruthenium Catalysts, In Topics in Organometallic Chemsitry 11, Ruthenium Catalysts and Fine Chemistry (Eds. C. Bruneau, P. H. Dixneuf), Springer-Verlag, Berlin Heiderberg, 2004, pp 81-92.

H. Nishiyama, K. Itoh, "Asymmetric hydrosilylation and related reactions" in Catalytic Asymmetric Synthesis, 2nd Ed., I. Ojima (Ed.), Wiley-VCH, New York, 2000, Chapter 2, 111-143.

Y. Motoyama, H. Nishiyama, Mg(II) and Zn(II) Lewis Acids, in "Lewis Acids-Application in Organic Synthesis", Ed. H. Yamamoto, Wiley-VCH Inc., New York, 2000, Vol. 1., Chapter 3, pp 58-88.

H. Nishiyama, Y. Motoyama, Other transition-metal reagents. Chiral transition-metal Lewis acid catalysis for asymmetric organic synthesis, in "Lewis Acid Reagents: A Practical Approach", Ed. H. Yamamoto, Oxford University Press (OUP), 1999, pp 225-243.

H. Nishiyama, Hydrosilylation of C=O and C=N in "Comprehensive Asymmetric Catalysis", Vol. 1, Eds. E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer, New York, 1999, pp 267-287.

H. Nishiayma, "Chiral bis(oxazolinyl)pyridine (PYBOX) ligands for asymmetric transition metal catalysis" in Advances in Catalytic Processes, VOl.2, M. P. Doyle (Ed.), "Asymmetric Catalysis", JAI Press Inc., 1997, 153-188.

西山久雄「8章 ロジウム」:「季刊化学総説 No.19, 1993:金属反応剤を用いる不斉化学合成」日本化学会編、学会出版センター、1993年, pp 91-101.

西山久雄、「第6章、Si,Sn化合物」、有機金属化合物・合成法および利用法、(編者山本明夫)東京化学同人、平成3年9月、p.p. 108-137.

西山久雄、伊藤健児、大学院有機化学(中)6.2. 典型金属・類金属化合物の反応、(編者 岩村、野依、中井、北川)講談社サイエンティフィック社、昭和63年6月、p.p. 385-404.

H. Brunner, H. Nishiyama, K. Itoh, In Catalytic Asymmetric Synthesis, I. Ojima (Ed.), VCH, New York, 1993, Chapter 6, 303.